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The Chemically enhanced process is considered to be a physicochemical technology for domestic wastewater treatment. The objective of this paper is to improve the efficiency of primary treatment processes and reducing the Hazardous Material and cost of the secondary treatment stage either by eliminating a biological treatment, where conditions and standards allow or by reducing the secondary treatment requirements. Analysis of physicochemical parameters as well as the treatment efficiency of aluminum sulfate (alum), ferric chloride (FeCl3), lime (CaO), and seawater was used. The effect of pH and the coagulant dosages were studied as well as mixing and settling time. Conditions were optimized according to the removal efficiencies measured in terms of reduction in the concentration of total suspended solids (TSS), biological oxygen demand (BOD5), and chemical oxygen demand (COD). The optimum COD removal % was achieved at a settling time of 20 minutes, while at pH~6, alum gave a high turbidity % removal of approximately 90% at the dose of 70 mg/l. FeCl3 gave a high turbidity % removal of approximately 95% at the dose of 40 mg/l. Turbidity removal and TSS removal gave a similar pattern at a settling time of 10-20 minutes, where best results were achieved. The results also showed that at pH~4, FeCl3 gave high COD% removal of approximately 90% at the dose of 40 mg/l. By studying the effect of stirrers' speed (rpm), the results showed that an increase in the mixing intensity, above 80 rpm decreases the removals of COD, Turbidity and TSS when using alum as a coagulant.
The Chemically enhanced process is considered to be a physicochemical technology for domestic wastewater treatment. The objective of this paper is to improve the efficiency of primary treatment processes and reducing the Hazardous Material and cost of the secondary treatment stage either by eliminating a biological treatment, where conditions and standards allow or by reducing the secondary treatment requirements. Analysis of physicochemical parameters as well as the treatment efficiency of aluminum sulfate (alum), ferric chloride (FeCl3), lime (CaO), and seawater was used. The effect of pH and the coagulant dosages were studied as well as mixing and settling time. Conditions were optimized according to the removal efficiencies measured in terms of reduction in the concentration of total suspended solids (TSS), biological oxygen demand (BOD5), and chemical oxygen demand (COD). The optimum COD removal % was achieved at a settling time of 20 minutes, while at pH~6, alum gave a high turbidity % removal of approximately 90% at the dose of 70 mg/l. FeCl3 gave a high turbidity % removal of approximately 95% at the dose of 40 mg/l. Turbidity removal and TSS removal gave a similar pattern at a settling time of 10-20 minutes, where best results were achieved. The results also showed that at pH~4, FeCl3 gave high COD% removal of approximately 90% at the dose of 40 mg/l. By studying the effect of stirrers' speed (rpm), the results showed that an increase in the mixing intensity, above 80 rpm decreases the removals of COD, Turbidity and TSS when using alum as a coagulant.
Desalination, 2007
In this study, the coagulation process is evaluated in treatment of municipal wastewater on the basis of organic material (e.g. chemical oxygen demand, COD) and suspended solids (TSS) removal efficiency. Alum-coagulation was optimized on the samples (24 sampling campaigns) taken from 4 wastewater treatment plants and a pilot plant at the University laboratory (Naples, Italy) to meet the Italian water quality discharge limits. A series of jar test experiments was run at 100 rpm for 1 min, 30 rpm for 20 min and 30 min for settling. 150 mg/l and 450 mg/l doses of alum were applied at pH ranging from 4 to 10 and room temperature. An anionic polyelectrolyte was used for flocculation. Raw and coagulated wastewater samples were analyzed for their COD, TSS and aluminium (RA) concentrations. The jar test experiments provided evidence that coagulation process could not provide sufficient COD removal efficiency in the Cuma and the University pilot plant wastewater even at an alum dose of 450 mg/l whereas the treatment with coagulation process using 150 mg/l alum in Nola and S. Giovanni plants was sufficient to meet COD (<160 mg/l) and TSS (80 mg/l) limits. The highest COD removal (80%) was obtained at the range of 6.0-8.0 pH values in the Nola plant, whereas COD removal was lesser in the Marcianese wastewater although its initial COD value was in the same order with the Nola plant. COD removal of the university plant improved from 55 to 75-85% in parallel to TSS removal by pH increase (up to 8.0). The statistical analyses showed different correlation values/behaviour between COD and TSS removals in each plant due to wastewater origin, pH and applied alum dose. RA was found significantly related to pH of coagulation process. RA concentration increased at pH value <5.0. These obtained results should contribute to, in particular, further RA studies dealing with the RA 114 M. Mattei et al. / Desalination 211 (2007) 113-127 risk in the coagulated effluents. Moreover, this study evidenced once again that coagulation process can assure the limits of COD, TSS and RA for municipal wastewater treatment plants if the process is well optimized and operated.
Modern Chemistry & Applications, 2017
Alum and ferrous sulphate, being among the best-known coagulants in water treatment were investigated with the aim of determining their coagulation efficiencies. The parameter levels of a turbid water were determined before and after treatment with alum and ferrous sulphate respectively at coagulant dosages of 1 to 10 g per 3 litres of turbid water, for each of the following parameters: pH, total suspended solids (TSS), dissolved oxygen (DO), biochemical oxygen demand (BOD5), turbidity, chloride, fluoride, phosphate and chemical oxygen demand (COD). The turbid water was prepared by addition of ground humus soil to tap water. Using a sedimentation beaker, experiments were conducted, leading to optimum coagulant dosage in some parameters. Coagulation experiments of the turbid water at the coagulant dosage of 10 g per 3 litres, gave the following coagulation efficiencies with alum as the coagulant: pH (44.92%), TSS (98.71%), DO (90.10%), BOD5 (100%), Turbidity (98.70%), chloride (100%), fluoride (100%), Phosphate (80%), COD (100 %) and Copper (0.00%). Similarly, using ferrous sulphate coagulant for the same level of turbid water and same dosage, the coagulation efficiencies achieved were: pH (57.24%), TSS (96.54%), DO (96.31%), BOD5 (100%), Turbidity (96.77%), and chloride (100%), fluoride (100%), phosphate (91.11%), COD (100%) and Copper (0.00%). The results showed that increasing coagulant dosage enhances water quality with respect to all the parameters studied. Furthermore, the results indicated that pH, DO, BOD5, fluoride, phosphate and COD mean % efficiencies were higher for ferrous sulphate coagulant in comparison with alum. On the other hand, alum displayed better coagulation efficiency than ferrous sulphate in the following parameters: TSS, turbidity and chloride. The overall results of the coagulation studies applying increasing coagulant dosage revealed that coagulant efficiency is parameter dependent. The outcome of this work can be an important guide to water treatment operators.
— Coagulation and flocculation followed by sedimentation are the customarily used unit operations in conventional water treatment process. Usually the process of coagulation is carried out using different metal salts such as aluminum and iron oxides. Therefore, this study was aimed at evaluating the performance of mix-chemical coagulants in water purification process. An experimental comparative study was done by evaluating controlled factors under various experimental setups. Jar tests were conducted to assess the efficiency of alum and ferric chloride coagulants in dual (1:1 and 3:1 alum to ferric chloride) combinations as well as separately. ANOVA tests were performed to select the best performing coagulant using Minitab version 16. The highest percentage TDS removal performance of 55.8%, 72.6%, 81.4% and 81.4% were exhibited for alum, ferric chloride, 1:1 and 3:1 alum-ferric chloride combination. And the highest percentage COD removal performance of 71%, 58.1%, 63.6%, and 50.9% was demonstrated for alum, ferric chloride, 1:1 and 3:1 alum-ferric chloride combination, respectively. The highest percentage turbidity removal performance shown by alum, ferric chloride, 1:1 and 3:1 alum-ferric chloride combination were 98.7%, 99.1%, 98.7% and 97.8%, respectively. The 1:1 alum-ferric chloride coagulant combination shows highest (80.8%) concurrent TDS, COD, and turbidity average removal. The result of this study indicated that 1:1 alum-ferric chloride was found the most suitable coagulant to perform the coagulation process for the removal of COD, TDS and turbidity simultaneously. The use of optimized alum-ferric chloride combinations as a coagulant is preferable to single coagulant use if appropriately managed.
American Journal of Environmental Sciences, 2010
Problem statement: Turbid waters, containing colloidal particles, are normally treated by coagulation-flocculation followed by clarification. Ferric chloride and alum, which are the most common types of coagulants in water treatment plants of Iran as well as many other countries, were investigated with the aim of determining their capabilities to reduce turbidity of drinking water. Turbidity was added as kaolin. Optimization of coagulation process may assure removal of turbidity to a level below water quality standards in most cases. Approach: In this study, the effectiveness of aluminum sulfate and ferric chloride was evaluated at different pH values and coagulant dosage to find optimal operational conditions for low to high turbidity waters. The influence of lime, as a coagulant aid, on coagulation process was also studied. A set of jar test experiments was conducted to find the optimal pH and coagulant dosage. Results: Results demonstrated that coagulation process can assure turbidity removal from low to medium turbidity waters effectively, using relatively low levels of aluminum sulfate and ferric chloride (10-20 mg L −1). Turbidity removal efficiency still remained high when the initial turbidities of water were increased to 500 and 1000 NTU. Conclusion/Recommendations: Results showed that turbidity removal is dependent on pH, coagulant dosage, as well as initial turbidity of water for both used coagulants. The highest turbidity removal efficiency was within 82.9-99.0% for alum and 92.9-99.4% for ferric chloride over the applied range of turbidity. Turbidity removal efficiency was higher for ferric chloride compared to aluminum sulfate at optimum conditions. Both applied coagulants demonstrated promising performance in turbidity removal from water. The results of the current study can be used as a baseline data for drinking water treatment facilities which uses these two types of coagulants.
This article was originally published in a journal published by Elsevier, and the attached copy is provided by Elsevier for the author's benefit and for the benefit of the author's institution, for non-commercial research and educational use including without limitation use in instruction at your institution, sending it to specific colleagues that you know, and providing a copy to your institution's administrator. All other uses, reproduction and distribution, including without limitation commercial reprints, selling or licensing copies or access, or posting on open internet sites, your personal or institution's website or repository, are prohibited. For exceptions, permission may be sought for such use through Elsevier's permissions site at: http://www.elsevier.com/locate/permissionusematerial Abstract The coagulation/flocculation process was used at laboratory bench scale for the removal of chemical oxygen demand (COD), total suspended solids (TSS) and total phosphorus (TP) in abattoir wastewater. The wastewater was allowed to settle for 24 h and TSS and TP removal efficiencies of 65% and 32% were achieved, respectively. Alum, ferric chloride and ferric sulfate were employed during the coagulation/flocculation process. Alum proved more effective in the reduction of TSS and TP present in the wastewater, whereas ferric sulfate was more effective in the reduction of COD. Increasing the dose of alum to 750 mg/l caused the removal efficiency of TP to reach 45%. The rate of removal of TP linearly increased with increasing doses of alum, resulting in a 98% removal efficiency of TP at 1000 mg/l dose of alum. At a 95% confidence interval, alum dose, coagulation velocity gradient/rapid mixing time (coagulation Gt) and flocculation velocity gradient/slow mixing time (flocculation Gt) were not significant for TSS removal efficiency, but alum dose was significant for TP removal. The addition of a polyelectrolyte to an inorganic coagulant proved effective in the reduction of COD, TSS and TP, cut the amount of coagulant used and reduced the cost of the coagulation/flocculation process. A significant degree of particle elimination by size was produced by using alum; this improved further with the addition the polyelectrolyte.
Journal of Environmental Sciences, 2011
A coagulation-flocculation process is typically employed to treat the industrial wastewater generated by the consumer products industry manufacturing detergents, soaps, and others. The expenditure of chemicals including coagulants and chemicals for pH adjustment is costly for treating this wastewater. The objective of this study was to evaluate the feasibility of reusing the aluminum sulfate (alum) sludge as a coagulant or as a coagulation aid so that the fresh alum dosage can be minimized or the removal efficiency can be enhanced. The experiments were conducted in a jar-test apparatus simulating the coagulation-flocculation process for simultaneous removals of organic matters, anionic surfactants, suspended solids, and turbidity. At the optimum initial pH value of 10 and the fresh alum concentration of 400 mg/L, the total suspended solids (TSS), total chemical oxygen demand (TCOD), total anionic surfactants, and turbidity removal efficiencies were 71.5%, 76.4%, 95.4%, and 98.2%, respectively. The addition of alum sludge as a coagulant alone without any fresh alum addition could significantly remove the turbidity, TCOD, and anionic surfactants. The TSS was left in the supernatants after the settling period, but would subsequently be removed by adding the fresh alum. The TSS, TCOD, and turbidity removal efficiencies were also enhanced when both the alum sludge and the fresh alum were employed. The TCOD removal efficiency over 80% has been accomplished, which has never fulfilled by using the fresh alum alone. It is concluded that the alum sludge could be reused for the treatment of industrial wastewater generated by the consumer products industry.
The prevailing most widely used method for coagulation and flocculation are dosages of Alum, copperas, lime, ferric chlorides, but the contaminants removal efficiency from above given Methods are not cost effective. Therefore, the present study focuses on use of different coagulants and flocculants such as conventional and non-conventional to reduce the contaminants from the wastewater. Various parameters (includes pH, COD, TDS, TSS) are to be studied before and after treatment with conventional and non-conventional coagulants respectively and to find out the effect of these coagulants on various effluents. These coagulants are compared with each other and may results in higher removal efficiency of contaminants.
The prevailing most widely used method for coagulation and flocculation are dosages of Alum, copperas, lime, ferric chlorides, but the contaminants removal efficiency from above given Methods are not cost effective. Therefore, the present study focuses on use of different coagulants and flocculants such as conventional and non-conventional to reduce the contaminants from the wastewater. Various parameters (includes pH, COD, TDS, TSS) are to be studied before and after treatment with conventional and non-conventional coagulants respectively and to find out the effect of these coagulants on various effluents. These coagulants are compared with each other and may results in higher removal efficiency of contaminants.
Nowadays many water resources are polluted by human activities including household and agricultural wastes and industrial processes. About 90% of the water we use on our daily basis is contaminated in one way or the other and this has a detrimental effect on human and aquatic lives. Here, we aim at the best possible ways of treating this wastewater using five different coagulants and also determining the efficiencies of the coagulants by varying their concentration. This practical was conducted using a conventional jar test apparatus. The sample was collected from an abattoir area very close to a shallowly dug well at Abakpa. 5ml of the coagulant was added to 20ml of the wastewater. The processes involved were rapid mixing (250rpm) for 3minutes, slow mixing (50rpm) for 10minutes, settling for 20minutes and filtration. The weight of the filter paper was measured before and after filtration for total suspended solid (TSS) calculation. It was found that Aluminium Sulphate was the best for the test as it produced a high TSS with the lowest concentration. The other coagulants were also good and can be used as alternatives to Aluminium Sulphates.
Verso la 3ª Assemblea Ecumenica di Sibiu, Romania - ROMA 24 • 21 GENNAIO 2005.
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