Papers by Andrzej Przyjazny
Green Analytical Chemistry
The paper presents a new procedure for assessing the polarity and hydrophobicity of deep eutectic... more The paper presents a new procedure for assessing the polarity and hydrophobicity of deep eutectic solvents (DESs) based on the measurement of the DES contact angle on glass. DESs consisting of benzoic acid derivatives and quaternary ammonium chlorides – tetrabutylammonium chloride (TBAC) and benzyldimethylhexadecylammonium chloride (16-BAC) in selected mole ratios were chosen for the study. To investigate the DESs polarity, an optical goniometer and an ET(30) solvatochromic scale based on the Reichardt’s dye were used. The research demonstrated the high accuracy and precision of the developed procedure. The simplicity of the examination and the availability of basic equipment allow the implementation of the developed procedure in routine investigations of DESs.
Social Science Research Network, 2022
preparation procedure for the determination of polycyclic aromatic hydrocarbons in petroleum vacu... more preparation procedure for the determination of polycyclic aromatic hydrocarbons in petroleum vacuum residue and bitumen
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2017
Liquid-phase microextraction (LPME) has emerged over the last 15–20 years as one of the simplest ... more Liquid-phase microextraction (LPME) has emerged over the last 15–20 years as one of the simplest and most easily implemented techniques of sample preparation in the determination of organic analytes in a variety of matrices. This article summarizes the historical developments and various modes of the technique, method development, recent trends, and selected applications.
Journal of Chromatography A, 2021
deep eutectic solvent-based (DES) stationary phase for gas chromatography and future perspectives... more deep eutectic solvent-based (DES) stationary phase for gas chromatography and future perspectives for DES application in separation techniques,
Renewable and Sustainable Energy Reviews, 2018
Journal of Chromatography A, 2019
Importance of volatile oxygenated organic compounds (O-VOC) analysis in effluents Comprehensive... more Importance of volatile oxygenated organic compounds (O-VOC) analysis in effluents Comprehensive review on GC applications for the determination of O-VOC in effluents Discussion on advantages and issues of each alternative analytical protocols Current trends and novelties in research of wastewater samples
Chemical Engineering and Processing - Process Intensification, 2018
This is a PDF file of an unedited manuscript that has been accepted for publication. As a service... more This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. Effective method of treatment of industrial effluents under basic pH conditions using acoustic cavitation-a comprehensive comparison with hydrodynamic cavitation processes
Journal of Chromatography A, 2018
deep eutectic solvents as "green" extraction media for polycyclic aromatic hydrocarbons in aqueou... more deep eutectic solvents as "green" extraction media for polycyclic aromatic hydrocarbons in aqueous samples,
Renewable and Sustainable Energy Reviews, 2018
Hydrogen applicability in the power, chemical and petrochemical industries is constantly growing.... more Hydrogen applicability in the power, chemical and petrochemical industries is constantly growing. Efficient methods of hydrogen generation from renewable sources, including waste products, are currently being developed, even though hydrogen is mainly produced through steam reforming or thermal cracking of natural gas or petroleum fractions. In paper alternative methods of hydrogen production with a particular emphasis on dark fermentation are discussed. The review compiles essential information on strains of bacteria used in the production of hydrogen from waste products in the agroindustry and from lignocellulosic biomass. The effect of such parameters as kind of raw material, method of processing, temperature, pH, substrate concentration, partial pressure of hydrogen, hydraulic retention time, method of inoculum preparation and the type and operating parameters of a reactor on the yield of dark fermentation is discussed. The review aims at presentation of current state of knowledge on the dark fermentation process utilizing waste materials as substrates. The results of investigations with emphasis on the most important issues regarding operating parameters of dark fermentation are also included. Highlights Hydrogen can be produced from biomass by biotechnological methods Utilization of lignocellulose within dark fermentation requires pretreatment Optimization of lignocellulosic biomass pretreatment improves fermentation results Improvement of the efficiency of hydrogen generation requires constant research Scale-up should result in high-potential strategies for hydrogen technologies
Ultrasonics sonochemistry, 2018
Cavitation has become on the most often applied methods in a number of industrial technologies. I... more Cavitation has become on the most often applied methods in a number of industrial technologies. In the case of oxidation of organic pollutants occurring in the aqueous medium, cavitation forms the basis of numerous advanced oxidation processes (AOPs). This paper presents the results of investigations on the efficiency of oxidation of the following groups of organic compounds: organosulfur, nitro derivatives of benzene, BTEX, and phenol and its derivatives in a basic model effluent using hydrodynamic and acoustic cavitation combined with external oxidants, i.e., hydrogen peroxide, ozone and peroxone. The studies revealed that the combination of cavitation with additional oxidants allows 100% oxidation of the investigated model compounds. However, individual treatments differed with respect to the rate of degradation. Hydrodynamic cavitation aided by peroxone was found to be the most effective treatment (100% oxidation of all the investigated compounds in 60 min). When using hydrodyna...
Journal of chromatography. A, Jan 22, 2018
The paper presents a new procedure for the determination of organic acids in a complex aqueous ma... more The paper presents a new procedure for the determination of organic acids in a complex aqueous matrix using ultrasound-assisted dispersive liquid-liquid microextraction followed by injection port derivatization and GC-MS analysis. A deep eutectic solvent (choline chloride: 4-methylphenol in a 1:2 mol ratio) was used both as an extracting solvent and as a derivatizing agent to yield ion pairs which were next converted to methyl esters of organic acids in a hot GC injection port. The procedure was optimized in terms of selection of a deep eutectic solvent, disperser solvent, and the ratio of their volumes, pH, salting out effect, extraction time, injection port temperature and time of opening the split valve. The developed procedure is characterized by low LOD (1.7-8.3 μg/L) and LOQ (5.1-25 μg/L) values, good repeatability (RSD ranging from 4.0 to 6.7%), good recoveries for most of the studied analyte (81,5-106%) and a wide linear range. The procedure was used for the determination of...
Ultrasonics Sonochemistry, 2018
Utilization of cavitation in advanced oxidation processes (AOPs) is a promising trend in research... more Utilization of cavitation in advanced oxidation processes (AOPs) is a promising trend in research on treatment of industrial effluents. The paper presents the results of investigations on the use of hydrodynamic cavitation aided by additional oxidation processes (O 3 /H 2 O 2 /Peroxone) to reduce the total pollution load in the effluent from the production of bitumens. A detailed analysis of changes in content of volatile organic compounds (VOCs) for all processes studied was also performed. The studies revealed that the most effective treatment process involves hydrodynamic cavitation aided by ozonation (40% COD reduction and 50% BOD reduction). The other processes investigated (hydrodynamic cavitation + H 2 O 2 , hydrodynamic cavitation + Peroxone and hydrodynamic cavitation alone) ensure reduction of COD by 20, 25 and 13% and reduction of BOD by 49, 32 and 18%, respectively. The results of this research revealed that most of the VOCs studied are effectively degraded. The formation of byproducts is one of the aspects that must be considered in evaluation of the AOPs studied. This work confirmed that furfural is one of the byproducts whose concentration increased during treatment by hydrodynamic cavitation alone as well as hydrodynamic cavitation aided by H 2 O 2 as an external oxidant and it should be controlled during treatment processes.
Journal of separation science, 2016
We present a new procedure for the determination of oxygenated volatile organic compounds in samp... more We present a new procedure for the determination of oxygenated volatile organic compounds in samples of postoxidative effluents from the production of petroleum bitumens using dispersive liquid-liquid microextraction and gas chromatography with mass spectrometry. The eight extraction parameters were optimized for 43 oxygenated volatile organic compounds. The detection limits obtained ranged from 0.07 to 0.82 μg/mL for most of the analytes, the precision was good (relative standard deviation below 2.91% at the 5 μg/mL level and 4.75% at the limit of quantification), the recoveries for the majority of compounds varied from 70.6 to 118.9%, and the linear range was wide, which demonstrates the usefulness of the procedure. The developed procedure was used for the determination of oxygenated volatile organic compounds in samples of raw postoxidative effluents and in effluents after chemical treatment. In total, 23 compounds at concentration levels from 0.37 to 32.95 μg/mL were identified ...
Journal of separation science, 2016
We present a new procedure for the determination of volatile organosulfur compounds in samples of... more We present a new procedure for the determination of volatile organosulfur compounds in samples of industrial effluents using dispersive liquid-liquid microextraction and gas chromatography with flame photometric detection. Initially, the extraction parameters were optimized. These included: type and volume of extraction solvent, volume of disperser solvent, salting out effect, pH, time and speed of centrifugation as well as extraction time. The procedure was validated for 30 compounds. The developed procedure has low detection limits of 0.0071-0.49 μg/L and a good precision (relative standard deviation values of 1.2-5.0 and 0.6-4.1% at concentrations of 1 and 10 μg/L, respectively). The procedure was used to determine the content of volatile organosulfur compounds in samples of effluents from the production of bitumens before and after chemical treatment, in which six compounds were identified, including 2-mercaptoethanol, thiophenol, thioanisole, dipropyl disulfide, 1-decanethiol, ...
Journal of separation science, Jan 6, 2017
We present a new procedure for the determination of 32 volatile organonitrogen compounds in sampl... more We present a new procedure for the determination of 32 volatile organonitrogen compounds in samples of industrial effluents with a complex matrix. The procedure, based on dispersive liquid-liquid microextraction followed by gas chromatography with nitrogen-phosphorus and mass spectrometric detection, was optimized and validated. Optimization of the extraction included the type of extraction and disperser solvent, disperser solvent volume, pH, salting out effect, extraction, and centrifugation time. The procedure based on nitrogen-phosphorus detection was found to be superior, having lower limits of detection (0.0067-2.29 μg/mL) and quantitation as well as a wider linear range. The developed procedure was applied to the determination of content of volatile organonitrogen compounds in samples of raw effluents from the production of bitumens in which 13 compounds were identified at concentrations ranging from 0.15 to 10.86 μg/mL and in samples of effluents treated by various chemical m...
Journal of Separation Science, 2016
We present the results of investigations on the possibility of the application of the asphaltene ... more We present the results of investigations on the possibility of the application of the asphaltene fraction isolated from the oxidized residue from vacuum distillation of crude oil as a stationary phase for gas chromatography. The results of the investigation revealed that the asphaltene stationary phases can find use for the separation of a wide range of volatile organic compounds. The experimental values of Rohrschneider/McReynolds constants characterize the asphaltenes as stationary phases of medium polarity and selectivity similar to commercially available phases based on alkyl phthalates. Isolation of asphaltenes from the material obtained under controlled process conditions allows the production of a stationary phase having reproducible sorption properties and chromatographic columns having the same selectivity. Unique selectivity and high thermal stability make asphaltenes attractive as a material for stationary phases for gas chromatography. A low production cost from a readily available raw material (oxidized petroleum bitumens) is an important economic factor in case of application of the asphaltene stationary phases for preparative and process separations.
Journal of Separation Science, 2016
We present the results of investigations of the chromatographic (sorptive) properties of silanize... more We present the results of investigations of the chromatographic (sorptive) properties of silanized silica gel as a stationary phase for gas chromatography used for simulated distillation. Commercially available silanized sorbent (particle diameter range 63-200 m, average pore size 60 Å) was sieved to obtain the 80-100 mesh fraction (180-150 m). The obtained results revealed that silanized silica gel allows the complete separation of a mixture of nand iso-alkanes in the C 1-C 7 range. Such a separation is achieved with a temperature program starting with an initial temperature of 50˚C, which is advantageous because the gas chromatograph oven does not have to be cooled below room temperature. The use of temperature programming with a final temperature of 300˚C ensures separation and elution of all mixture components from C 1 to n-C 28 in one run. This study confirms the applicability of silanized silica gel as a stationary phase for the investigation of distillation temperature distribution of gasoline and diesel fuel based on the simulated distillation procedure according to ASTM D2887. The deviations of individual points of distillation curve obtained using ASTM D2887 and columns packed with silanized silica gel were within the reproducibility range of the standard procedure.
Journal of Chromatography A, Mar 12, 2004
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Papers by Andrzej Przyjazny