Edible bird's nest of the swiftlet Aerodramus fuciphagus, is an unusual dried mucin glycoprotein,... more Edible bird's nest of the swiftlet Aerodramus fuciphagus, is an unusual dried mucin glycoprotein, which has been used, particularly by Asians, as a premium food and wide spectrum health supplement for centuries. For the first time, thermogravimetry, differential thermogravimetry, and differential scanning calorimetry methods are used for the rapid identification and authentication of edible bird's nest. It is shown that edible bird's nest has a total moisture content of 12.6% which is removed below 200°C, followed by two major decomposition steps on heating under nitrogen gas. The first decomposition step (200-735°C) has a mass loss of 68.0% with maximum rate of mass loss at about 294°C, and the second decomposition step (735-1000°C) has a mass loss of 15.4% with maximum rate of mass loss at about 842°C, leaving a ceramic residue of about 4.0%. Differential scanning calorimetry shows that there are two kinds of bound water in edible bird's nest: (a) loosely bound water (about 7.5%) that dehydrates from edible bird's nest first, largely below 110°C, which can also be removed by lyophilization, and (b) tightly bound water (about 5.0%), still present in the edible bird's nest after lyophilization, that dehydrates from edible bird's nest between 100 and 200°C. The unique thermogravimetry and differential thermogravimetry curves of edible bird's nest serve as analytical standards and offer a simple, fast technique that requires only a small sample size (5-10 mg) without the need for sample pretreatment to authenticate and check for edible adulterants which may be introduced into edible bird's nest with a profit motive.
The difference between the swiftlet white edible bird's nest from limestone caves versus house-fa... more The difference between the swiftlet white edible bird's nest from limestone caves versus house-farmed ones, especially in response to high temperature and stewing time in water where the latter type would disintegrate readily, has been a puzzle for a long time. We show that edible bird's nests from the limestone caves have calcite deposits on the surface of the nest cement as compared to the house-farmed nests which are built by swiftlets on timber planks. The micron and sub-micron calcite particles are seen in SEM-EDX and further characterized by ATR-FTIR and Raman microspectroscopy. The calcite deposits make it possible for the cave nest to retain a gelatinous texture under the harsh retort conditions at 121°C for 20 mins in commercial bottling. We show that house-farmed nests can be soaked in CaCl2(aq) followed by rinsing with Na2CO3(aq) to grow the same calcite deposits on the nest cement with the same characteristic as cave nests. Therefore, there should no longer be a need to harvest cave nests, and we can better conserve the dwindling population and natural habitats of cave swiftlets.
Edible bird's nest of the swiftlet Aerodramus fuciphagus, is an unusual dried mucin glycoprotein,... more Edible bird's nest of the swiftlet Aerodramus fuciphagus, is an unusual dried mucin glycoprotein, which has been used, particularly by Asians, as a premium food and wide spectrum health supplement for centuries. For the first time, thermogravimetry, differential thermogravimetry, and differential scanning calorimetry methods are used for the rapid identification and authentication of edible bird's nest. It is shown that edible bird's nest has a total moisture content of 12.6% which is removed below 200°C, followed by two major decomposition steps on heating under nitrogen gas. The first decomposition step (200-735°C) has a mass loss of 68.0% with maximum rate of mass loss at about 294°C, and the second decomposition step (735-1000°C) has a mass loss of 15.4% with maximum rate of mass loss at about 842°C, leaving a ceramic residue of about 4.0%. Differential scanning calorimetry shows that there are two kinds of bound water in edible bird's nest: (a) loosely bound water (about 7.5%) that dehydrates from edible bird's nest first, largely below 110°C, which can also be removed by lyophilization, and (b) tightly bound water (about 5.0%), still present in the edible bird's nest after lyophilization, that dehydrates from edible bird's nest between 100 and 200°C. The unique thermogravimetry and differential thermogravimetry curves of edible bird's nest serve as analytical standards and offer a simple, fast technique that requires only a small sample size (5-10 mg) without the need for sample pretreatment to authenticate and check for edible adulterants which may be introduced into edible bird's nest with a profit motive.
The difference between the swiftlet white edible bird's nest from limestone caves versus house-fa... more The difference between the swiftlet white edible bird's nest from limestone caves versus house-farmed ones, especially in response to high temperature and stewing time in water where the latter type would disintegrate readily, has been a puzzle for a long time. We show that edible bird's nests from the limestone caves have calcite deposits on the surface of the nest cement as compared to the house-farmed nests which are built by swiftlets on timber planks. The micron and sub-micron calcite particles are seen in SEM-EDX and further characterized by ATR-FTIR and Raman microspectroscopy. The calcite deposits make it possible for the cave nest to retain a gelatinous texture under the harsh retort conditions at 121°C for 20 mins in commercial bottling. We show that house-farmed nests can be soaked in CaCl2(aq) followed by rinsing with Na2CO3(aq) to grow the same calcite deposits on the nest cement with the same characteristic as cave nests. Therefore, there should no longer be a need to harvest cave nests, and we can better conserve the dwindling population and natural habitats of cave swiftlets.
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