Examen Ordinario Termoquimica - Emmanuel Gonzalez Flores
Examen Ordinario Termoquimica - Emmanuel Gonzalez Flores
Examen Ordinario Termoquimica - Emmanuel Gonzalez Flores
Ti ci hi
i [°C ] [kJ/kg °C] [kJ/kg]
1 65 4.185 272.025
2 28 4.18 117.04
3 12 4.20 50.4
ṁ1 = 3.5 [kg/s]
Respuestas:
a) El flujo masico de aire a la entrada es d
ṁa = 5.41
b) Agua de reposición:
ṁ3 = 0.18
de aire a la entrada es de:
[kga/s]
[kgl/s]
Datos iniciales:
P= 74 [kPa] TBg = 30 [°C] EA =
R= 8.3145 [KJ/kmol K] Ta = 15 [°C] j=
T0 = 298 [K] Tgc = 427 [°C]
P0 = 100 [kPa] Tgc = 700 [K]
Vgn = 400 [m3/d] Ṅgn = 11.74 [kmol/d]
0.0046 [m /s]
3
Entrada
i Sustancia PMi nij Ṅi°
[kgi/kmol] 1 2 3 [kmol/d]
1 CH4 16 -1 0 0 7.986
2 H2 2 0 -1 0 0.211
3 H2S 34 0 0 -1 0.799
72.784
N2 28 0 0 0
4 0.141
5 CO2 44 1 0 0 2.466
1.468
6 H2O 18 2 1 1
0.141
7 SO2 64 0 0 1 0.000
8 O2 32 -2 -0.5 -1.5 19.348
PMGN = 23.02 [kg/kmol] PMa = 28.97 [kg/kmol]
rGN = 0.6758 [kg/m3]
ℎ_𝑖=ℎ_(𝑓,𝑖)^0+
288.15 303.15 298.15 700.15
i Sustancia h°f,i hi,T [kJ/kmol]
[kJ/kmol] 15 30 25 427
* 1 CH4 -74,840 10,313.42 10,849.59 10,669.97 29,327.71
* 2 H2 0 8,179.71 8,638.31 8,468.00 20,218.50
* 3 H2S -20,150 10380.54 10897.73 10725.26 25375.90
* 4 N2 0 8,378.16 8,814.60 8,669.00 20,604.00
* 5 CO2 -393,500 8,995.20 9,549.40 9,364.00 27,125.00
* 6 H2O -285,400 9,564.02 10,071.84 9,904.00 24,088.00
* 7 SO2 -296,900 9594.59 10192.09 9991.97 28549.53
* 8 O2 0 8,388.70 8,828.60 8,682.00 21,184.00
15000
10000
35000
30000
f(x) = − 8.58072527865868E-06 x³ + 0.0266334402889902 x²
25000 R² = 0.99999991105656
360 2538 2537.56 20000
380 3387 3387.94
15000
400 4250 4251.81
420 5126 5128.74 10000
440 6015 6018.33 5000
460 6917 6920.16
480 7831 7833.83 0
100 200 300 400 500 6
500 8758 8758.92 -5000
550 11123 11118.91
-10000
600 13544 13541.28
650 16022 16019.58
700 18548 18547.40
750 21117 21118.28
800 23721 23725.80
850 26369 26363.51
CH4
900 29023 29024.99
950 31714 31703.79
30000
Metano (CH4): 25000 f(x) = − 5.735540897841E-08 x⁴ + 0.000111730968694 x³ − 0
+ 3927.05078076623
T [K] h R² = 0.999999998699023
111.51 8190.8 8190.85 20000
200 11209 11208.80
15000
300 14663 14663.37
400 18475 18474.63 10000
500 22831 22831.18
5000
600 27784 27783.96
0
0 100 200 300
H2S
Sulfuro de Hidrogeno (H2S)
40000
10000
5000
0
100 200 300 400 50
288.15 303.15 700.15
i Sustancia s°i,T [kJ/kmol×K] si,T [kJ/kmol×K]
15 30 427 15 30 427
1 CH4 --- 78.62 112.76 --- 84.335 ---
2 H2 --- 131.04 --- --- 166.946 ---
3 H2S --- 65.02 --- --- 89.879 ---
4 N2 190.50 191.98 216.75 157.355 231.257 222.272
5 CO2 --- 214.29 250.66 --- 229.770 272.334
6 H2O 187.50 189.20 218.61 186.812 228.477 235.496
7 SO2 --- --- 106.35 --- --- 149.407
8 O2 204.02 --- 231.35 181.891 --- 266.475
SS =
𝑆_𝑔𝑒𝑛=𝑆_𝑠𝑎𝑙−𝑆_𝑒𝑛𝑡+𝑄_𝑠𝑎𝑙/𝑇_𝑎𝑙𝑟
Sgen =
160
140
f(x) = − 1.192462627207
Metano (CH4): + 29.2834112503
120
T [K] h s R² = 0.99998456008513
111.51 8190.8 8190.85 73.456 73.47210434 100
200 11209 11208.80 93.427 93.35775534
300 14663 14663.37 107.41 107.5400326 80
20
0
0 100
T [K] h s 140
212.6 18615 18611.8856 87.55 87.60999761
f(x) = − 3.272657155157
300 21640 21625.37087 99.486 99.68727459 120 + 35.038830962243
400 25146 25105.55638 109.56 110.2921958 R² = 0.99999758446116
500 28794 28687.75789 117.7 119.366837 100
600 32611 32396.0354 124.65 128.1963982
700 36607 36206.44891 130.81 137.3460794 80
60
40
20
0
100 200
j Reacciónes
1 CH4 + 2O2 ® CO2 + 2H2O
2 H2 + 1/2 O2 ® H2O
3 H2S + 3/2 O2 ® SO2 + H2O
Respuestas:
a) Composición de gases de combustión:
69.6% N2
10.0% CO2
17.7% H2O
0.8% SO2
2.0% O2
b) Relación Aire-Combustible:
Condiciones de solución: AC = 9.83 [kga/kgc]
0.12 - Combustión completa.
0.68 - Gas ideal. c) Tasa de transferencia de calor
- Estado estacionario. Qsal = 72.07 [kW]
d) Entropía generada:
Entrada Salida Sgen = 0.33 [kW/K]
xi° Ṅi xi
[kmol/d] e) Exergía destruída
0.680 0 Xdest = 97.7 [kW]
0.018 0
0.068 0
0.778
72.925 0.696
0.012
0.210 10.452 0.100
0.016
18.590 0.177
0.012
0.000 0.799 0.008
0.207 2.073 0.020
Ṅgc = 104.838
𝐻=∑▒ 〖𝑁 ̇ _𝑖∙ℎ_𝑖 〗
ℎ_𝑖=ℎ_(𝑓,𝑖)^0+(ℎ_(𝑖,𝑇)−ℎ_𝑖^0)
SO2
CH4
H2S
16,658.32 24,105.10
28,340.93 [kJ/K d]
8,445,598 [kJ/d]
Chart Title
50
00
f(x) = − 1.2439030136225E-10 x⁴ + 3.57777193864606E-07 x³ − 0.00041759932945767 x² + 0.303203546798423 x
+ 186.319400158311
50 R² = 0.999940453600728
00
50
00
50
0
100 200 300 400 500 600 700 800 900 1000
Entropia
160
140
f(x) = − 1.19246262720729E-09 x⁴ + 2.12240571264459E-06 x³ − 0.00142979811725145 x² + 0.530974816398827 x
120 + 29.2834112503
R² = 0.999984560085133
100
80
60
40
20
0
0 100 200 300 400 500 600 700
Chart Title
40
80
60
40
20
0
100 200 300 400 500 600 700 800
Datos iniciales:
Tm = 25 [°C] EA =
Ta = 15 [°C] j=
0.15
0.68
1077
hi [kJ/kmol] s°i,T [kJ/kmol×K]
15 804 15 804
-95,812.69 -36,539.51 112.76 -39.58