Apendices

0.082054 It· atm' oK-I. mol-1

82.057 em3. atm' °K-1 . mol-1
8.3144 J .oK-l. mol-1
8.3144 x 107 erg' °K-1 . mol-1
1.9872 eal· °K-1 . mol-1
Constante de Boltzmann 1.38044 x 10-16 erg' °K-1
Constante de Faraday 23040 eal· volt-1
96 400 J . volt-1
6.6252 x 10-27 erg' seg
1.58346 x 10-37 Keal . seg
Aeeleraeion de Ia gravedad g= 980.665 em . seg-2
Carga eleetroniea e= 4.80286 x 10-10 ues
Numero de Avogadro N= 6.023 x 1023
Veloeidad de la luz e= 299793 Km' seg-1

Longitud 1 m = 3.28084 pies = 39.3701 pulg

Masa 1 Kg = 2.204621b
Volumen 1 It = 0.0353147 pies3 = 0.264172 gal
Fuerza 1N = 1 Kg' m . seg-2 = 105 dinas = 0.224809 Ib fuerza
Presion 1 atm 6 2
= 760 mm Hg = 1.01325 x 10 dina . em- = 1.01325 bar
= 14.696 Ib . pulg-2
= 0.239006 eal = 1 Kg' m2 . seg-2 = 1 N . m = 1 W' seg
= 107 dina . em = 107 erg = 10 em3 . bar = 9.86923 em3 . atm
= 0.00987 It· atm = 9.47831 x 10-4 Btu
= 103 J . seg-1 = 1.34102 HP = 103 V' A = 103 Kg' m2 . seg3
= 239.006 eal· seg-1 = 737.562 pie ·Ibf 'seg-1
= 56.8699 Btu . min-1
 208 Termodinamica bio/6gica

Apendice 3. Datos termodinamicos de elementos y compuestos inorganicos a

condiciones de 298 oK y 1 atm.

~HO ~GO so cpo

Sustancia Estado (kJ mol-I) (kJ mol-I) (J mol-10K-I) (J mol-10K-I)

Ag sol 0 0 42.71 25.49

Ag+ aq 105.90 77.11 73.93 37.66
Agel sol -127.04 -109.72 96.11 50.79
AgBr sol -99.50 -95.94 107.11 52.38
Agi sol -62.38 -66.32 114.22 54.43
AgN03 sol -123.14 -32.18 140.92 93.05
AI sol 0 0 28.32 24.34
AP+ aq -524.67 -481.16 - 313.38
AI203 sol -1669.79 -1576.41 50.99 78.99
Ar gas 0 0 154.7 4 20.79
As sol 0 0 35.15 24.98
AS043- aq -870.27 -635.97 -144.77
AsH3 gas 171.54
H3As04 sol -900.40
Au sol 0 0 47.70 25.23
AU203 sol 80.75 163.18 125.52
AuCI sol -35.15
AuCI3 sol -118.41
B sol 0 0 6.53 11.97
B203 sol 1263.57 1184.07 54.02 62.26
H3B03 sol -1087.84 -963.16 89.58 82.05
aq -1067.76 -963.32 159.83
Ba sol 0 0 66.94 26.36
Ba2+ aq -538.36 -560.66 12.55
BaO sol -558.15 -528.44 70.29 47.45
BaCI2 sol -860.06 -810.86 125.52 75.31
BaS04 sol -1464.4 -1353.11 132.21 101.75
BaC03 sol -1218.80 -1138.88 112.13 85.35
Be sol 0 0 9.54 17.82
BeO sol -610.86 -581.58 14.10 25.40
Br2 1iq 0 0 152.30
!
Br- aq -120.92 102.82 80.71 -128.45
HBr gas -36.23 -53.22 198.48 29.12
C sol (grafito) 0 0 5.69 8.64
sol (diamante) 1.90 2.87 2.44 6.06
CO gas -110.52 -137.27 197.91 29.14
CO2 gas -393.51 -394.38 213.64 37.13
aq -412.92 -386.23 121.34
C032- aq -676.26 -528.10 -53.14
HC03- aq -691.11 -:587.06 94.98
 Apendices 209

~HO ~GO SO Cpo

Sustancia Estado (kJ mol-1) (kJ mol-1) (J mol-1 °K-l) (J mol-1 °K-l)

H2C03 aq -699.65 -623.17 187.44

CS2 gas 115.27 65.06 237.82 45.65
1iq 87.86 63.60 151.04 75.73
HCN aq 105.44 112.13 128.87
CN- aq 151.00 165.69 117.99
CNO- aq -140.16 -98.74 130.12
NH4HC03 sol -852.28
CO(NH2h sol -333.19 -197.15 104.60 93.14
aq -319.24 -203.84 173.85
Ca sol 0 0 41.63 26.28
Ca2+ aq -542.96 -553.04 -55.23
CaO sol -635.55 -604.17 39.75 42.80
Ca(OHh sol -986.59 -896.76 76.15 84.52
CaF2 sol -1214.62 -1161.90 68.87 67.03
CaCb sol -794.96 -750.19 113.81 72.63
CaS04 sol -1432.69 -1320.30 106.69 99.58
CaC03 sol (calcita) -1206.88 -1128.76 92.89 81.88
Cd sol 0 0 51.46 25.90
Cd2+ aq -72.38 -77.74 -61.09
CdO sol -254.64 -225.06 54.81 43.43
CdCI2 sol -389.11 -342.59 118.41
CdS04 sol -926.17 -820.20 137.24
Cb gas 0 0 222.95 33.93
HCI gas -92.31 -95.27 186.68 29.12
Co sol 0 0 28.45 25.56
C02+ aq -67.36 -51.46 155.23
CoO sol -239.32 -213.38 43.93
Cr sol 0 0 23.77 23.35
Cr2+ aq -138.91
Cr203 sol -1128.43 -1046.84 81.17 118.74
Cr042- aq -863.16 -706.26 38.49
Cr2072- aq -1460.63 -1257.29 213.80
Cs sol 0 0 82.84 31.05
Cs+ aq -247.69 -282.04 133.05
Cu sol 0 0 33.31 24.47
Cu+ aq 51.88 50.21 -26.36
Cu2+ aq 64.39 64.98 98.74
CuO sol -155.23 -127.19 43.51 44.35
CU20 sol -166.69 -146.36 100.83 69.87
CuCI sol -134.73 -118.83 91.63
CuCb sol -205.85
CuS sol -48.53 -48.95 66.53 47.82
CUS04 sol -769.86 -661.91 113.39 100.83
F2 gas 0 0 203.34 31.46
210 Termodinamica bio/6gica

~HO ~GO SO Cpo

Sustancia Estado (kJ mol-I) (kJ mol-I) (J mol-10K-I) (J mol-10K-I)

F- aq -329.11 -276.48 -9.62 -123.43

HF gas -268.61 -270.71 173.51 29.08
Fe sol 0 0 27.15 25.23
Fe2+ aq -87.86 -84.94 -113.39
Fe3+ aq -47.70 -10.54 -293.30
Fe203 sol -822.16 -740.99 89.96 104.60
Fe(OH12 sol -568.19 -483.55 79.50
Fe(OHh sol -824.25
H gas -217.94 203.24 114.61 20.79
H2 gas 0 0 130.59 28.84
H+ aq 0 0 0 0
OH- aq -229.94 -157.30 -10.54 -133.89
H2O gas -241.83 -228.60 188.72 33.58
H2O 1iq -285.84 -237.19 69.94 75.30
H202 1iq -187.61 -118.11
H202 aq -191.13
He gas 0 0 126.05 20.79
Hg 1iq 0 0 77.40 27.82
Hg2+ aq -164.38
HgO sol (rojo) -90.71 -58.53 71.97 45.73
HgCI2 sol -230.12
Hg2C12 sol -264.93 -210.66 196.22 101.67
HgS sol (rajo) -58.16 -48.83 77.82
HgS04 sol -704.17
Hg2S04 sol -741.99 -623.92 200.75 132.01
12 sol 0 0 116.73 54.98
1+ aq 55.94 51.67 109.37 -129.70
HI gas 25.94 1.30 206.33 29.16
K sol 0 0 63.60 29.16
K+ aq -251.21 -282.28 102.50
K20 sol -361.50
KOH sol -425.85
KCI sol -435.87 -408.33 82.68 51.51
KCI03 sol -391.20 -289.91 142.97 100.25
KCI04 sol -433.46 -304.18 151.04 110.17
$
KBr sol -392.17 -379.20 96.44 53.64
KI sol -327.65 -322.29 104.35 55.06
KN03 sol -492.71 -393.13 132.93 96.27
K2C03 sol -1146.12
Kr gas 0 0 163.97 20.79
Li sol 0 0 28.03 23.64
Li+ aq -278.46 -293.80 14.23
Li20 sol -595.80
LiOH sol -487.23 -443.92 50.21
 Apendices 211

AHO AGo So Cpo

Sustancia Estado (kJ mol-1) (kJ mol-1) (J mol-1 °K-l) (J mol-1 °K-l)

Mg sol 0 0 32.51 23.89

Mg2+ aq -461.96 -456.01 -117.99
MgO sol -601.83 -569.57 26.78 37.41
Mg(OHh sol -924.66 -833.75 63.14 77.03
MgCb sol -641.83 -592.33 89.54 71.30
MgS04 sol -1278.21 -1173.61 91.63 96.27
MgC03 sol -1112.94 -1029.26 65.69 75.52
Mn sol 0 0 31.76 26.32
Mn2+ aq -218.82 -223.43 -83.68
Mn3+ aq -100.42
Mn02 sol -520.91 -466.10 53.14 54.02
N2 gas 0 0 191.49 29.12
N3- aq 245.18
NH3 gas -46.19 -16.64 192.51 35.66
NH4+ aq -132.80 -79.50 112.84
NH4C1 sol -315.39 -203.89 94.56 84.10
NH40H aq -366.10 -263.76 181.17 -68.62
N2H4 1iq 50.42
NO gas 90.37 86.69 210.62 29.86
NO~ gas 33.85 51.84 240.46 37.91
N204 gas 9.66 98.29 304.30 79.08
N20 gas 81.56 103.60 219.99 38.70
HN02 aq -118.83 -53.64
HN03 1iq -173.22 -79.90 155.60 109.87
N03- aq -206.57 -110.50 146.44
Na sol 0 0 51.05 28.41
Na+ aq -239.66 -261.87 60.25
Na20 sol -415.89 -376.56 72.80 68.20
NaCI sol -411.00 -384.03 72.38 49.71
NaBr sol -359.95 52.30
Nal sol -288.03 54.39
Na2S04 sol -1384.49 -1266.83 149.49 127.61
NaN03 sol -466.68 -365.89 116.32 93.05
Na2C03 sol -1130.94 -1047.67 135.98 110.50
NaHC03 sol -947.68 -851.86 102.09 87.61
Ne gas 0 0 146.22 20.79
Ni sol 0 0 30.13 25.98
Ni2+ aq -64.02 -46.44 159.41
NiO sol -244.35 -216.31 38.58 44.35
Ni(OHh sol -538.06 -453.13 79.50
0 gas 247.52 230.10 160.95 21.91
02 gas 0 0 205.03 29.36
03 aq -12.09 16.32 110.88 167.40
gas 142.26 163.43 237.65 38.16
212 Termodinamica bio/6gica

LlHo LlGO SO Cpo

Sustancia Estado (kJ mol-I) (kJ mol-I) (J mol-1 OK-I) (J mol-10K-I)

P sol (blanco) 0 0 44.00 23.22

sol (rajo) -18.40 13.82 29.31
P043- aq -1284.07 -1025.59 -217.57
PZ074- aq -2275.68
P40IQ sol -3012.48
PH3 gas 9.25 18.24 210.04
HP04z- aq -1298.71 -1094.12 -35.98
HzP04- aq -1302.48 -1135.12 89.12
H3P04 sol -1281.14
H4PZ07 sol -2250.99
Pb sol 0 0 64.89 26.82
Pbz+ aq 1.63 24.31 21.34
PbO sol (amarillo) -217.86 -188.49 69.45 48.53
PbOz sol -276.65 -218.99 76.57 64.43
PbCl2 sol -359.20 -313.97 136.40 76.99
PbS sol -94.31 -92.68 91.21 49.50
PbS04 sol -918.40 -811.24 147.28 104.18
PI sol 0 0 41.84 26.57
PICI4z- aq -516.31 -384.51 175.73
Rb sol 0 0 69.45 30.42
Rb+ aq -246.44 -282.21 124.27
S sol (r6mbico) 0 0 31.88 22.59
sol (monoclinico) 0.30 0.10 32.55 23.64
SOz gas -296.06 -300.37 248.52 39.79
S03 gas -395.18 -370.37 256.22 50.63
S03Z- aq -624.25 -497.06 43.51
S04Z- aq -907.51 -741.99 17.15
HzS gas -20.15 -33.02 205.64 33.97
HS03- aq -627.98 -527.31 132.38
HS04- aq -885.75 -752.87 126.86
HzS04 1iq -811.32
SF6 gas -1096.21
Se sol 0 0 42.44 25.36
SeOz sol -225.35
HzSe gas 29.71 15.90 218.91 34.73
!
HZSe04 sol -530.11
Si sol 0 0 18.70 19.87
SiOz sol (cuarzo) -859.30 -805.00 41.84 44.43
Sr sol 0 0 54.39 25.10
Srz+ aq -545.51 -557.31 39.33
SrC!z sol -828.43 -781.15 117.15 79.08
SrS04 sol -1444.74 -1334.28 121.75
SrC03 sol -1218.38 -1137.63 97.07 81.42
W sol 0 0 33.47 24.98
 Apendices 213

LiHO LiGo SO Cpo

Sustancia Estado (kJ mol-1) (kJ mol-1) o mol-1 °K-l) o mol-1 °K-l)

W03 sol -840.31 -763.45 83.26 81.50

W04- aq - 1115.45
Xe gas 0 0 169.58 20.79
Zn sol 0 0 41.63 25.06
Zn2+ aq -152.42 -147.21 106.48
ZnO sol -347.98 -318.19 43.93 40.25
ZnCl2 sol -415.89 -369.26 108.37 76.57
ZnS sol -202.92 -198.32 57.74 45.19
ZnS04 sol -978.55 -871.57 124.68 117.15

Los valores de esta tabla fueron tomados de Selected Values of Chemical Thermodynamics
Properties, por F. D. Rossini y colaboradores, publicado por la "National Bureau of Standards",
NBS Circular 500, (1952), asi como de NBS Technical Notes 270-3 (1968) Y 270-4 (1969),
editado por D. D. Wagman y colaboradores. Todos 105 valores estan referidos a 1 mol de
material en el estado fisico indicado, a 1 atm de presion y a 298.15 oK de temperatura. Los
valores para los iones en solucion acuosa (1 M) estan basad os en la convencion de que todas
las propiedades enlistadas para H+(aq) son igual a cera. De donde, con la adicion de valores
para combinaciones neutras de iones con cargas opuestas, se obtiene los valores correctos
para soluciones de sa!.

Apendice 4. Datos termodinamicos de compuestos organicos y mo/ecu/as

bio/6gicas a 298.15 oK y 1 atm.

LiHO LiGO So cp
Compuesto Formula Estado (KJ/mol) (KJ/mol) OtK mol)OtK mol)

Acido acetico CH3COOH liq -484.21 -389.45 159.83

Acido acetico CH3COOH liq -484.21 -389.45 159.83
aq -485.26 -404.09 205.43
buf -485.60 -417.52 249.37
Acido DL-aspartico C4H704N sol -976.96 -729.27 154.39
Acido L-aspartico C4H704N sol -972.53 -729.36 170.12 155.27
buf -943.41 -736.51 291.63
Acido L-aspartico, ion C4HB04N+ aq -955.17 -733.87 229.28
Acido L-aspartico, ion dipolar C4H704N+- aq -947.43 -718.06 216.31
Acido L-aspartico, ion dipolar C4H604N+2- aq -943.41 -695.88 155.65
Acido butirico C4H302 liq -535.13 -379.07 226.35 179.49
aq -532.62 -399.57 303.76
buf -535.55 -412.54 320.91
Acido a-cetoglutarico CSH60S sol -1026.34
214 Termodinamica bio/6gica

ilHo ilGo So Cp
Compue?to Formula Estado (KJ/mol) (KJ/mol) OrK mol)OrK mol)

Acido citrico C6Ha07 sol -1543.90

buf -1515.78 -1288.63 512.54
Acido citico, monohidrato C6H100a sol -1838.45 -1473.56 283.47 268.15
Acido f6rmico HCOOH liq -409.20 -346.02 128.95 99.04
Acido fumarico C4H404 sol -810.65 -653.25 166.11 142.26
aq -774.88 -645.80 261.08
buf -777.39 -684.38 381.99
Acido L-glutamico CsHg04N sol -1009.18 -730.95 188.20 175.23
buf -981.98 -721.87 248.95
Acido L-glutamico, ion CSH1004N+ aq -981.57 -734.63 293.72
Acido L-glutamico, ion dipolar CSH904N+- aq -981.99 -721.87 248.95
Acido L-glutamico, ion dipolar CsHa04N+z- aq -979.89 -697.47 174.05
Acido L(+)-Iactico C3H603 sol -694.04 -523.25 143.51 127.61
aq -686.22 -538.77 221.75
buf -686.64 -557.35
Acido DL-Iactico C3H603 liq -673.62 -518.82 192.05 211.29
Acido L-malico C4H60S sol -1103.32
aq -891.61
buf -925.08
Acido DL-malico C4H6OS sol -1105.41
Acido oxalacetico C4H40S sol -984.50
aq -832.62
buf -875.71
Acido palmitico C16H3Z0Z sol -890.77 -315.06 455.22 460.66
aq -287.86
buf -299.16
Acido piruvico C3H403 liq -585.76
aq -607.52 -486.60 179.91
buf -596.22 -513.38
Acido succinico C4H604 sol -940.81 -747.35 175.73 153.97
aq -912.20 -746.64 269.45 230.12
buf -908.72 -772.99 369.45
Acetato CH3COO- aq -485.60 -376.89 112.97
Acetato de etilo C4HaOz liq -481.99 -337.65 262.76 105.44
Acetaldehido CH3CHO gas -246.81 -139.08 264.22 56.07
Acetona CH3COCH3 liq -246.81 -153.55 198.74 126.78
Acetileno CzHz gas 226.73 209.20 200.83 43.93
Adenina CsHsNs sol 97.07 -300.41 151.04 143.09
DL-Alanina C3H70ZN sol -563.59 -371.96 132.21 121.75
L-Alanina C3H70zN sol -562.75 -370.20 129.20 122.26
buf -554.80 -371.16 158.99
L-Alanina, ion C3HaOzN+ aq -557.94 -384.55 192.05 288.70
L-Alanina, ion dipolar C3H70Z+- aq -554.80 -371.16 158.99 141.00
L-Alaninato, ion C3H60zN- aq -509.61 -314.85 121.75 71.55
L-Arginina C6H140ZN4 sol -621.74 -656.89 250.62 233.47
 Apendices 215

ilHO ilGO So Cp
Compuesto Formula Estado (KJ/mol) (KJ/mol) OrK mol) OrK mol)

L-Arginina, ion dipolar C6H1402N4+- aq -615.47

L-Aspartato, ion C4Hs04N2- aq -905.84 -638.69 89.96
L-Asparagina C4H803N2 sol -790.36 -530.95 174.47 160.67
L-Asparagina, ion dipolar C4H803N2+- aq -766.09 -525.93 238.91
L-Asparagina, monohidrato C4H1004N2 sol -1085.75 -767.35 209.62 207.95
Benceno C6H6 1iq 49.04 172.80 124.52
Butirato, ion C4HzOz- aq -535.55 -372.04 201.67
a-Cetoglutarato, ion CsH4Oz- aq -793.41
L-Cistefna C3H70zNS sol -532.02 -342.67 169.87 173.22
buf 338.95
L-Cisteina, ion C3H80zNS+ aq -349.36
L-Cisteina, ion dipolar C3H70zNS+- aq -338.82
L-Cisteinato, ion monovalente C3H60zNS- aq -290.99
L-Cisteinato, ion divalente C3HsOzNSz- aq -229.58
L-Cistina C6H lZ04NzSz sol -1044.33 -685.76 280.58 261.92
buf -668.19
L-Cistina, ion C6H1404Nzsi+ aq 684.50
L-Cistina, ion dipolar C6H 1304NzSz+- aq -678.23
L-Cistina, ion dipolar C6H lZ04NzS2+2- aq -666.51
L-Cistinato, ion C6H 1004NzS2- aq -562.33
Citra to, ion monovalente C6H707- aq -1520.88 -1226.33 286.19 187.86
Citra to, ion divalente C6H707Z- aq -1518.46 -1199.18 203.34 0.84
Citra to, ion trivalente C6Hs073- aq -1515.11 -1162.69 92.05 -254.81
Creatinina C4H70N3 sol -237.65 -28.45 167.36 138.91
Creatinina, ion C4HaON3+ aq 4.14
Creatina C4H90zN3 sol -536.47 -264.01 189.54 171.96
aq -259.20
buf -259.20
Creatina, cation C4H100zN3+ aq -274.39
Creatina, anion C4H80ZN3- aq -177.82
Creatina, monohidrato C4Hl103N3 sol -833.03 -504.59 234.30 213.38
Etano CZH6 gas -84.68 -32.89 229.49 52.66
Etanol C2HSOH liq -276.98 -174.18 161.04 111.96
Etileno CZH4 gas 52.30 68.12 219.45 43.56
Formato, ion HCOO- aq -410.03 -334.72 91.63
Fumarato, ion monovalente C4H304- aq -774.46 -628.14 203.34
Fumarato, ion divalente C4Hz04z- aq '-777.39 -601.87 105.44
Glicerol C3H803 liq -670.70 -479.49 204.60 216.73
Glicina CZHS02N sol -537.23 -377.69 103.51 99.20
buf -523.00 -379.91 158.57
Glicina, ion C2H60zN+ aq -527.18 -393.30 189.54 171.54
Glicina, ion dipolar C2HSOzN+- aq ':'523.00 -379.91 158.57 36.82
Glicinato, ion C2H4OzN- aq -478.65 -324.09 120.50 54.81
Glicilglicina C4H803NZ sol -746.01 -491.50 189.95 163.59
buf -734.25 -493.08 232.21
Glicilglicina, ion C4H903Nz+ aq -735.72 -510.87 286.60 288.70
216 Termodinamica bi%gica

tJ.HO tJ.Go So Cp
Compuesto Formula Estado (Kl/mol) (Kl/mol) (JrK mol) (JrK mol)

Glicilglicina, ion dipolar C4H803N2+- aq -734.25 -492.08 231.38 158.99

Glicilglicinato, ion C4H703N2- aq -689.90 -445.76 222.17
a-D-Glucosa C6H1206 sol -1274.45 -910.56 212.13 218.87
aq -1263.06 -914.54 264.01
~-D-Glucosa C6H1206 sol -1268.05 -908.89 228.03
aq -1264.24 -915.79 264.01
a-~-D-Glucosa C&H1206 aq -1263.78 -916.97 269.45 305.43
a-D-Glucosa, monohidrato C&H1407 sol -1571.09 -1149.55 252.30
Glucosa- 1-fosfato C&H1309P aq -1789.50
buf -1828.83
Glucosa- 1-fosfato, ion monovalente C3H1209P- aq -1783.22
Glucosa- 1-fosfato, ion divalente C3H1209P2- aq -1746.11
Glucosa-6-fosfato C6H1309P aq -1797.45
Glucosa-6-fosfato, ion monovalente C6H1209P- aq -1789.08
Glucosa-6-fosfato, ion divalente C6Hl109p2- aq -1753.51
L-Glutamato CSH704N2- aq -939.73 -643.50 127.61
L-Glutamina CSHlOO3N2 sol -825.92 -532.21 195.10 183.80
buf -805.00 -528.02 251.04
L-Glutamina, ion dipolar CSHlOO3N2+- aq -805.00 -528.02 251.04
L(+)-Lactato, ion C3HS03- aq -686.64 -516.72 146.44
a-Lactosa C12Hn011 sol -2221.70
aq -2232.37 -1564.90 394.13
~-Lactosa C12HnOIl sol -2236.77 -1566.91 386.18 410.45
a, ~- Lactosa C12HnOI1 aq -2233.09 -1567.33 399.57
DL-Leucina C6H1302N sol -649.78 -358.57 207.11 195.39
L-Leucina C6H1302N sol -646.85 -356.48 209.62 208.36
buf -643.37 -352.25 206.69
L-Leucina, ion C6H1402N+ aq -645.01 -365.56 246.44 -660.24
L-Leucina, ion dipolar C6H1302N+- aq -643.37 -352.25 207.53 506.26
L-Leucinato, ion C6H1202N- aq -600.61 -296.60 164.43 447.69
Malato, ion monovalente C4HsOS- aq -871.95
Malato, ion divalente C4H40S2- aq -842.66
a-Maltosa C12Hn011 aq -2238.27 -1573.60 403.34
~-Maltosa C12HnOll aq -2237.73 -1572.18 400.41
a,~-Maltosa C12HnOll aq -2238.06 -1574.69 407.94
~-Maltosa, monohidrato C12H24012 sol -2539.27 -1809.58 417.56 453.96
Metano CH4 gas -74.85 -50.79 186.19 35.73
Metanol CH30H liq -238.66 -166.31 126.78 81.59
aq -245.89 -175.23 132.34
L-Metionina CSH1I02NS sol -761.07 -508.36 231.46 290.20
L-Metionina, ion CSH1202NS+ aq -744.75
L-Metionina, ion dipolar CsH 1102NS+- aq -744.33
Oxaloacetato, ion monovalente C4H30S- aq -818.39
Oxaloacetato, ion divalente C4H20s2- aq -793.29
Palmitato, ion Cl&H3102- aq -259.41
 Apendices 217

~HO ~GO SO Cp
Compuesto Formula Estado (KJ/mol) (KJ/mol) OrK mol) OtK mol)

Piruvato, ion C3H303- aq -596.22 -472.37 171.54

2-Propanol C3H70H liq -317.86 -180.29 180.58 154.22
aq -330.83 -185.23 153.55
Succinato, ion monovalente C6HS04- aq -908.89 -722.62 199.99 96.23
Succinato, ion divalente C6H4042- aq -908.68 -690.44 92.88 122.59
Sacarosa C12H22011 sol -2221.70 -1544.31 360.24 425.51
aq -2215.85 -1551.43 403.76 633.04
DL-Valina CSH1102N sol -617.98 -359.82 181.17
buf -617.98 -358.65 176.98
L-Valina, ion CSHI202N+ aq -612.24 -371.71 240.16 547.27
L- Valina, ion dipolar CSH1102N+- aq -611.99 -358.65 176.98 389.11
L-Valinato, ion CSH1002N- aq -567.43 -307.40 174.89 333.88

Los datos de esta tabla fueron obtenidos de R.C. Wilhoit "Thermodynamic properties of biochemical
substances" publicados en Biochemical Microcalorimetry, editado por HD. Brown, capitulo 2,
Academic Press Inc., New York, 1969.
EI simbolo buf significa los valores en el equilibrio de una soluci6n amortiguadora 0 tamp6n a pH 7. Las
concentraciones de las soluciones acuosas son todas de 1 M.