Fracción mol Fracción peso CpA

T °C TK XA YA XA YA (kCal/Kg°C)
100 373.15 0 0 0.00 0.00 0.5975
74.8 347.95 0.05 0.6381 0.15 0.85 0.5667
68.53 341.68 0.1 0.7301 0.26 0.90 0.5598
65.26 338.41 0.15 0.7716 0.36 0.92 0.5564
63.59 336.74 0.2 0.7916 0.45 0.92 0.5547
61.87 335.02 0.3 0.8124 0.58 0.93 0.5529
60.75 333.9 0.4 0.8269 0.68 0.94 0.5518
59.95 333.1 0.5 0.8387 0.76 0.94 0.5510
59.12 332.27 0.6 0.8532 0.83 0.95 0.5502
58.29 331.44 0.7 0.8712 0.88 0.96 0.5494
57.49 330.64 0.8 0.895 0.93 0.96 0.5486
56.68 329.83 0.9 0.9335 0.97 0.98 0.5478
56.3 329.45 0.95 0.9627 0.98 0.99 0.5474
56 329.15 1 1 1.00 1.00 0.5471

Diagrama de equilibrio Acetona-Agua. Fracción peso. 1

1.0
Composición en fase vapor de A (y)

Teb °C 0.9
Acetona (A) 56 0.8
Agua (B) 100 0.7
0.6
0.5
PM Acetona 58 Kg/kmol
0.4
PM Agua 18 Kg/kmol 0.3
0.2
0.1
Cp's Perry 0.0
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.8
Componente A
C1 C2 C3 C4 C5 Composición en fase líquida de A (x)
1.36E+05 -1.77E+02 2.84E-01 6.89E-04 0
Componente B
C1 C2 C3 C4 C5
2.76E+05 -2.09E+03 8.125 -1.41E-02 9.37E-06

Calores de vaporización Perry

Componente A
C1x1E-07 C2 C3 C4
4.215 0.3397 0 0
42150000 0.3397 0 0
Componente B
C1x1E-07 C2 C3 C4
5.2053 0.3199 -0.212 0.25795
52053000 0.3199 -0.212 0.25795

Temperatura crítica (K)

Componente A 508.2
Componente B 647.13
 CpB Cp mezcla hLiq TrA TrB lambda A Lambda B Lambda mezcla
(kCal/Kg°C) (kCal/Kg°C) (kCal/Kg) K K (kCal/Kg) (kCal/Kg) (kCal/Kg)
1.0103 1.0103 101.03 0.734 0.577 110.84 542.25 542.254
1.0035 0.9401 70.32 0.685 0.538 117.47 557.21 183.284
1.0022 0.8856 60.69 0.672 0.528 119.01 560.72 164.471
1.0017 0.8403 54.84 0.666 0.523 119.80 562.51 157.047
1.0014 0.8021 51.01 0.663 0.520 120.20 563.42 153.676
1.0012 0.7412 45.86 0.659 0.518 120.61 564.36 150.281
1.0010 0.6945 42.19 0.657 0.516 120.87 564.96 147.962
1.0009 0.6576 39.42 0.655 0.515 121.06 565.39 146.086
1.0008 0.6274 37.09 0.654 0.513 121.25 565.83 143.790
1.0007 0.6023 35.11 0.652 0.512 121.45 566.28 140.962
1.0007 0.5811 33.41 0.651 0.511 121.63 566.70 137.270
1.0006 0.5629 31.90 0.649 0.510 121.82 567.13 131.454
1.0005 0.5547 31.23 0.648 0.509 121.91 567.33 127.203
1.0005 0.5471 30.64 0.648 0.509 121.98 567.49 121.980

tona-Agua. Fracción peso. 1 atm. Diagrama Entalpía-Composición. Acetona-Agua. 1 atm.

700
600
500
Entalpía (kCal/kg)

400
300
200
100
0
.40 0.50 0.60 0.70 0.80 0.90 1.00 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
ón en fase líquida de A (x) Composición

Fracción peso CpA CpB

T°C TK XA XB (kcal*kmol°C) (kcal*kmol°C)
F 25 298.15 0.54 0.46 0.52 1.00
D 45 318.15 0.93 0.07 0.54 1.00
W 98.1 371.25 0.05 0.95 0.59 1.01
 Hvap
(kCal/Kg)
643.283
253.606
225.161
211.884
204.682
196.139
190.153
185.507
180.884
176.073
170.678
163.359
158.433
152.619

. 1 atm.

0.80 0.90 1.00

Cp mez h mez
(kcal*kmol°C) (kcal*kmol)
0.74 18.56
0.57 25.62
0.99 97.02
 Fracción mol
F(lb/min)= 3500 T °C TK XA YA
F(Kg/h)= 95254.511 100 373.15 0 0
XF (Mol)= 0.28 74.8 347.95 0.05 0.6381
XD (Mol)= 0.80480769 68.53 341.68 0.1 0.7301
XW (Mol)= 0.01607143 65.26 338.41 0.15 0.7716
Tf= 25 63.59 336.74 0.2 0.7916
61.87 335.02 0.3 0.8124
PM Acetona 58 Kg/kmol 60.75 333.9 0.4 0.8269
PM Agua 18 Kg/kmol 59.95 333.1 0.5 0.8387
59.12 332.27 0.6 0.8532
Fracciones en peso 58.29 331.44 0.7 0.8712
XFacetona= 0.55616438 57.49 330.64 0.8 0.895
XDacetona= 0.93 56.68 329.83 0.9 0.9335
Xwacetona= 0.05 56.3 329.45 0.95 0.9627
56 329.15 1 1
Flujo para acetona en F
F(Kg/h)= 52977.1664 Teb °C
F(Kmol/h) 913.39942 Acetona (A) 56
Flujo para el agua en F Agua (B) 100
F(kg/h)= 42277.3446
F(Kmol/h)= 2348.74137 Cp's Perry
Flujo total en F Componente A
F(kmol/h)= 3262.14079 C1 C2 C3 C4
Flugo D 1.36E+05 -1.77E+02 2.84E-01 6.89E-04
D(kmol/h)= 1091.58434 Componente B
Flujo en W C1 C2 C3 C4
W(Kmol/h)= 2170.55644 2.76E+05 -2.09E+03 8.125 -1.41E-02

Fracción mol
T°C TK XA
F 25 298.15 0.28000
D 45 318.15 0.80481
W 98.1 371.25 0.01607
 Linea de 45
X Y
0 0
1 1 1.2

Linea XW
1
X Y
0.01607143 0
0.8
0.01607143 0.01607143

0.6
Linea XF
0.28 0
0.4
0.28 0.28

Linea XD 0.2

X Y
0.80480769 0 0
0 0.2 0.4
0.80480769 0.80480769

Calores de vaporizació
Componente A
C1x1E-07
C5 4.215
0 4.33E+07
Componente B
C5 C1x1E-07
9.37E-06 5.2053
52053000
Fracción mol CpA CpB Cp mez h mez
XB kcal/kmolºK kcal/kmolºK (kcal*kmol°C) (kcal/kmol)
0.72000 30.18821 18.01726 21.42512 535.62811
0.19519 31.11645 17.98176 28.55266 1284.86977
0.98393 34.47538 18.15680 18.41907 1806.91043

Pman= 1.5

Pabs= 2.53323

P (kgf/cm^2) Landa (Kcal/Kg)

X Y
2.3663 522.1
 2.754 518.6
2.53323 520.59302295589

Landa (Kcal/Kmo9370.6744132061
 1
0.95
0.9
0.85
2 0.8
0.75
0.7
1 0.65
0.6
0.55
8
0.5
0.45
6 0.4
0.35
0.3
4 0.25
0.2
0.15
2
0.0999999999999998
0.0499999999999998
0 -2.56739074444567E-16
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4
-0.0500000000000003

Calores de vaporización Perry

Componente A
C2 C3 C4
0.3397 0 0
0.3766 0 0
Componente B
C2 C3 C4
0.3199 -0.212 0.25795
0.3199 -0.212 0.25795

Temperatura crítica (K)

Componente A 508.2
Componente B 647.13
T ebullicion
Tr acetona= 0.527
Tr agua= 0.4607265928 0.3766 Linea q y leida=
x y XD=
Landa v acetona= 4273.6628442 kcal/kmol 0.28 0.28 Rmin=
Landa v agua= 6290.559473 kcal/kmol 0.2 0.88967308 R=

Landa de mezcla= 5725.828417 kcal/kmol

f= -0.115996988 0.11599699

mx b
q= -7.620913465 2.41385577
 1
0.95
0.9
0.85
0.8
0.75
0.7
0.65
0.6
0.55
0.5
0.45
0.4
0.35
0.3
0.25
0.2
0.15
0.0999999999999998
0.0499999999999998
-2.56739074444567E-16
0 0.2 0.4 0.6
0.2 0.4 0.6 0.8 1 1.2 -0.0500000000000003

0.79 Ecuacion de R Linea q

0.80480769 mx b x y
0.01874391 y= 0.04476224 0.7687827 0.28 0.28
0.04685979 0.2145 0.77916983
Linea de
enrequecimiento
X Y
0.80480769 0.80480769
0 0.7687827
 1
0.95
0.9
0.85
Plato 1
0.8 2
Plato
0.75
0.7
Plato 3 0.65
0.6
0.55
0.5
0.45
0.4
0.35
0.3
0.25
0.2
Plato 4
0.15
0.2 0.4 0.6 0.8 1 1.2 0.0999999999999998
0.0499999999999998
-2.56739074444567E-16
0 0.2 0.4 0.6
-0.0500000000000003

Enrequecimiento Empobrecimiento
X Y X Y
0.80480769 0.80480769 0.01607143 0.01607143
0.214 0.77836182 0.214 0.77836182
 Plato 1

0.2 0.4 0.6 0.8 1 1.2