Instituto Politcnico Nacional

Escuela Superior de Ingeniera Qumica e

Industrias Extractivas
Laboratorio de Operaciones de Separacin Por
Etapas

RECTIFICACIN POR LOTES

DE UNA MEZCLA BINARIA
Reporte de prctica

Profesor:
Hctor Zamorano Garca
Alumno:
Baruch Enrique
Rodrguez Balderas
Grupo: 3IV76
Equipo:
5
Mxico, D.F.; a 20 de octubre de

OBJETIVOS

Comprender el comportamiento de una rectificacin por lotes en una

mezcla binaria realizada en una columna adiabtica.
Aplicar el Mtodo de Mc Cabe Thiele para el sistema etanol agua, en el
proceso de rectificacin por lotes.
Cuantificar la separacin de una mezcla una operacin por lotes.

INTRODUCCIN

La destilacin Batch o discontinua es un proceso ampliamente utilizado para la

separacin de pequeas cantidades de mezclas, la recuperacin de pequeas
cantidades de materiales peligrosos en corrientes de desechos, la recuperacin de
solventes, as
como para la obtencin de productos farmacuticos y
biotecnolgicos de alto valor agregado entre otros, por tanto, el desarrollo de
modelos matemticos para la prediccin del comportamiento del proceso es un
trabajo que ha ganado inters a lo largo de los ltimos tiempos.
Una columna de destilacin Batch o discontinua puede operar utilizando
cualquiera de las siguientes polticas: reflujo constante, reflujo variable y reflujo
ptimo. El comportamiento del proceso puede predecirse mediante la utilizacin
de modelos matemticos basados en los balances de materia y energa. Los
modelos matemticos que se obtienen pueden clasificarse como modelos
simplificados (mtodos cortos), modelos semi - rigurosos, modelos rigurosos y
modelos de reduccin de orden.
En la actualidad la obtencin de modelos rigurosos es un campo de mucho
inters sobre todo porque las computadoras actuales cuentan con un alta
precisin y capacidades de procesamiento mayores, sin embargo, el uso
generalizado de equipos tales como las tabletas y/o computadoras porttiles de
menor capacidad de procesamiento de datos, hacen factible la bsqueda de
mtodos simplificados que puedan predecir el comportamiento de los procesos
sin tener que recurrir a mayor capacidad de procesamiento. Aunado a esto,
siempre ser necesario contar con este tipo de mtodos para obtener datos
iniciales para el proceso de optimizacin matemtica.

CALCULOS
Tablas de datos experimentales
Alimentaci
n

h (cm)

Hervidor

17.9

Reflujo
Total
Residuo
XWRT
Destilado
XDRT
Corte 1
Residuo
XW1
Destilado
XD1
Corte 2
Residuo
XW2
Destilado
XD2
Corte 3
Residuo
XW3
Destilado
XD3
Corte 4
Residuo
XW4
Destilado
XD4

V(lts)
22

V(lts)

2.56
V(lts)

1.144
V(lts)

0.330
V(lts)

0.244
V(lts)

0.200

( cmgr )

0.984

% X peso

X0 mol

0.0329

W0 mol

( cmgr )

% X peso

Xmol

0.971

17

0.0742

0.935

38

0.1934

% X peso

Xmol

0.976

12.5

0.0529

0.845

77

0.5671

% X peso

Xmol

0.979

11

0.0461

0.854

72.5

0.5078

% X peso

Xmol

0.985

0.0244

0.855

71

0.4893

% X peso

Xmol

0.985

0.0244

0.870

68

0.454

( cmgr )
3

( cmgr )
3

( cmgr )
3

( cmgr )
3

Corte 5
Residuo
XWF
Destilado
XDF

V(lts)

0.430

gr
3
cm

( )

% X peso

Xmol

.985

0.0244

0.867

67.5

0.4483

Construccin del Diagrama

Para Comportamiento Ideal
Calculo de la presin de saturacin del etanol:
7.5867

1281.59
93.2051+193.768

7.5867

1281.59
95.7558+193.768

7.5867

1281.59
98.3064+193.768

7.5867

1281.59
100.8571 +193.768

7.5867

1281.59
103.4077 +193.768

P 0 eta=10
P 0 eta=10
P 0 eta=10

P 0 eta=10
P 0 eta=10

=1320.7212mmHg

7.5867

1281.59
105.9584 +193.768

7.5867

1281.59
108.5090 +193.768

7.5867

1281.59
111.0597+193.768

7.5867

1281.59
113.6103 +193.768

7.5867

1281.59
116.1610 +193.768

P 0 eta=10

=1445.9552 mmHg P 0 eta=10

.=1580.5614 mmHg P 0 eta=10

=1725.0377 mmHg P 0 eta=10
=1879.8956 mmHg P 0 eta=10

=2045.6598 mmHg
=2222.8683mmHg
=2412.0720 mmHg
=2613.8341 mmHg
=2828.7302 mmHg

Calculo de la presin de saturacin del agua:

1730.63
93.2051+233.426

8.07131

1730.63
95.7558+233.426

8.07131

1730.63
98.3064+233.426

8.07131

1730.63
100.8571+233.426

8.07131

1730.63
103.4077+233.426

P 0 agua=10

8.07131

P 0 agua=10
P 0 agua=10
P 0 agua=10
P 0 agua=10

1730.63
105.9584+233.426

8.07131

1730.63
108.5090+233.426

8.07131

1730.63
111.0597+233.426

8.07131

1730.63
113.6103+233.426

8.07131

1730.63
116.1610+233.426

=592.7701 mmHg P 0 agua=10

8.07131

=651.5398 mmHg P 0 agua=10

=715.0959 mmHg P 0 agua=10

=783.7377 mmHg P 0 agua=10

=857.7769 mmHg P 0 agua=10

Calculo de la composicin del etanol en la fase liquida

=937.5375 mmHg
=1023.3563 mmHg
=1115.5828 mmHg
=1214.5793 mmHg
=1320.7212 mmHg

Xeta=(1320.7212 mmHg592.7701 mmHg)/(1320.7212mmHg592.7701mmHg)=1.0000

Xeta=(1320.7212 mmHg651.5398 mmHg )/(1445.9552 mmHg651.5398 mmHg)=0.8424

Xeta=(1320.7212 mmHg715.0959 mmHg )/(1580.5614 mmHg715.0959 mmHg)=0.6998

Xeta=(1320.7212 mmHg783.7377 mmHg )/(1725.0377 mmHg783.7377 mmHg)=0.5705

Xeta=(1320.7212 mmHg857.7769mmHg )/(1879.8956 mmHg857.7769mmHg)=0.4529

Xeta=(1320.7212 mmHg937.5375mmHg )/(2045.6598 mmHg937.5375 mmHg)=0.3458

Xeta=(1320.7212 mmHg1023.3563 mmHg)/(2222.8683 mmHg1023.3563 mmHg)=0.2479

Xeta=(1320.7212 mmHg1115.5828 mmHg) /(2412.0720 mmHg1115.5828 mmHg)=0.1582

Xeta=(1320.7212 mmHg1214.5793 mmHg)/(2613.8341 mmHg1214.5793 mmHg)=0.0759

Xeta=(1320.7212 mmHg1320.7212 mmHg)/(2828.7302mmHg1320.7212mmHg )=0.0000

Calculo de la composicin del etanol en la fase vapor

Yeta=

1.00001320.7212 mmHg
=1.0000
1320.7212 mmHg

Yeta=

0.34582045.6598 mmHg
=0.5356
1320.7212 mmHg

Yeta=

0.84241445.9552 mmHg
=0.9222
1320.7212 mmHg

Yeta=

0.24792222.8683 mmHg
=0.4172
1320.7212 mmHg

Yeta=

0.69981580.5614 mmHg
=0.8374
1320.7212mmHg

Yeta=

0.15822412.0720 mmHg
=0.2890
1320.7212 mmHg

Yeta=

0.57051725.0377 mmHg
=0.7451
1320.7212 mmHg

Yeta=

0.07592613.8341mmHg
=0.1501
1320.7212 mmHg

Yeta=

0.45291879.8956 mmHg
=0.6447
1320.7212 mmHg

Yeta=

0.00002828.7302mmHg
=0.0000
1320.7212 mmHg

Para Comportamiento No Ideal

@T =93.2051 C

1.61981.0000
=1.0000
0.9227(11.0000 )
Cv=exp

0.92271.0000 2
=2.5161
1.6198(11.0000 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg592.7701 mmHg2.5161

=1.0000
1320.7212 mmHg1.0000592.7701 mmHg2.5161

YV =

1320.7212mmHg1.00001.0000
=1.0000
1320.7212 mmHg

@T =95.7558 C

1.61980.8424 2
=1.0151
0.9227(10.8424 )
Cv=exp

0.92270.8424 2
=2.1244
1.6198(10.8424 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg651.5398 mmHg2.1244

=0.7573
1445.9552 mmHg1.0151651.5398 mmHg2.1244

YV =

1445.9552mmHg0.75731.0151
=0.8416
1320.7212 mmHg

(
(

0.92270.7573
=7379.9593
1.6198(10.7573 )
Cp=exp

0.9227 1+

XV =

1.61980.7573
=732872128137.3923
0.9227(10.7573 )
Cv=exp

1.6198 1+

1320.7212 mmHg651.5398 mmHg7379.9593

=0.0000
1445.9552 mmHg732872128137.3923651.5398 mmHg7379.9593

YV =

1445.9552mmHg0.0000732872128137.3923
=3639.6907
1320.7212 mmHg

1.61980.0000 2
=5.0521
0.9227(10.0000 )
Cv=exp

0.92270.0000 2
=1.0000
1.6198(10.0000 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg651.5398 mmHg1.0000

=0.1006
1445.9552 mmHg5.0521651.5398 mmHg1.0000

YV =

1445.9552mmHg0.10065.0521
=0.5563
1320.7212 mmHg
2

1.61980.1006
=3.1013
0.9227(10.1006 )
Cv=exp

0.92270.1006
=1.0252
1.6198(10.1006 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

YV =

1320.7212 mmHg651.5398 mmHg1.0252

=0.1710
1445.9552 mmHg3.1013651.5398 mmHg1.0252

1445.9552mmHg0.17103.1013
=0.5808
1320.7212 mmHg

1.61980.1710 2
1.6198 1+
=2.3938
0.9227(10.1710 )
Cv=exp

0.92270.1710 2
0.9227 1+
=1.0674
1.6198(10.1710 )
Cp=exp

XV =

1320.7212 mmHg651.5398 mmHg1.0674

=0.2261
1445.9552 mmHg2.3938651.5398mmHg1.0674

YV =

1445.9552mmHg0.22612.3938
=0.5925
1320.7212 mmHg

1.61980.2261 2
=2.0295
0.9227(10.2261 )
Cv=exp

0.92270.2261 2
=1.1118
1.6198(10.2261 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg651.5398 mmHg1.1118

=0.2698
1445.9552 mmHg2.0295651.5398mmHg1.1118

YV =

1445.9552mmHg0.26982.0295
=0.5995
1320.7212 mmHg
2

1.61980.2698
=1.8148
0.9227(10.2698 )
Cv=exp

0.92270.2698
=1.1535
1.6198(10.2698 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.1535

=0.3040
1445.9552 mmHg1.8148651.5398 mmHg1.1535

YV =

1445.9552mmHg0.30401.8148
=0.6039
1320.7212 mmHg

1.61980.3040 2
1.6198 1+
=1.6804
0.9227(10.3040 )
Cv=exp

0.92270.3040 2
0.9227 1+
=1.1898
1.6198(10.3040 )
Cp=exp

XV =

1320.7212 mmHg651.5398 mmHg1.1898

=0.3297
1445.9552 mmHg1.6804651.5398 mmHg1.1898

YV =

1445.9552mmHg0.32971.6804
=0.6066
1320.7212mmHg

1.61980.3297 2
=1.5943
0.9227(10.3297 )
Cv=exp

0.92270.3297 2
=1.2191
1.6198(10.3297 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2191

=0.3484
1445.9552 mmHg1.5943651.5398 mmHg1.2191

YV =

1445.9552mmHg0.34841.5943
=0.6081
1320.7212mmHg

1.61980.3484 2
=1.5388
0.9227(10.3484 )
Cv=exp

0.92270.3484 2
=1.2415
1.6198(10.3484 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2415

=0.3614
1445.9552 mmHg1.5388651.5398 mmHg1.2415

YV =

1445.9552mmHg0.36141.5388
=0.6089
1320.7212mmHg

1.61980.3614 2
1.6198 1+
=1.5031
0.9227(10.3614 )
Cv=exp

0.92270.3614 2
0.9227 1+
=1.2576
1.6198(10.3614 )
Cp=exp

XV =

1320.7212 mmHg651.5398 mmHg1.2576

=0.3703
1445.9552 mmHg1.5031651.5398 mmHg1.2576

YV =

1445.9552mmHg0.37031.5031
=0.6093
1320.7212 mmHg

1.61980.3703 2
=1.4803
0.9227(10.3703 )
Cv=exp

0.92270.3703 2
=1.2687
1.6198(10.3703 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2687

=0.3761
1445.9552 mmHg1.4803651.5398 mmHg1.2687

YV =

1445.9552mmHg0.37611.4803
=0.6095
1320.7212 mmHg
2

1.61980.3761
=1.4658
0.9227(10.3761 )
Cv=exp

0.92270.3761
=1.2762
1.6198(10.3761 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2762

=0.3798
1445.9552 mmHg1.4658651.5398 mmHg1.2762

YV =

1445.9552mmHg0.37981.4658
=0.6096
1320.7212 mmHg

1.61980.3798 2
1.6198 1+
=1.4566
0.9227(10.3798 )
Cv=exp

0.92270.3798 2
0.9227 1+
=1.2811
1.6198(10.3798 )
Cp=exp

XV =(1320.7212mmHg651.5398 mmHg1.2811)/(1445.9552 mmHg1.4566651.5398 mmHg1.2811)=

YV =

1445.9552mmHg0.38221.4566
=0.6096
1320.7212 mmHg

1.61980.3822 2
=1.4509
0.9227(10.3822 )
Cv=exp

0.92270.3822 2
=1.2842
1.6198(10.3822 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg651.5398 mmHg1.2842

=0.3838
1445.9552 mmHg1.4509651.5398 mmHg1.2842

YV =

1445.9552mmHg0.38381.4509
=0.6096
1320.7212 mmHg
2

1.61980.3838
=1.4472
0.9227(10.3838 )
Cv=exp

0.92270.3838
=1.2862
1.6198(10.3838 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2862

=0.3847
1445.9552 mmHg1.4472651.5398 mmHg1.2862

YV =

1445.9552mmHg0.38471.4472
=0.6096
1320.7212 mmHg

1.61980.3847 2
1.6198 1+
=1.4450
0.9227(10.3847 )
Cv=exp

0.92270.3847 2
0.9227 1+
=1.2875
1.6198(10.3847 )
Cp=exp

XV =

1320.7212 mmHg651.5398 mmHg1.2875

=0.3854
1445.9552 mmHg1.4450651.5398 mmHg1.2875

YV =

1445.9552mmHg0.38541.4450
=0.6096
1320.7212mmHg

1.61980.3854 2
=1.4435
0.9227(10.3854 )
Cv=exp

0.92270.3854 2
=1.2883
1.6198(10.3854 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg651.5398 mmHg1.2883

=0.3857
1445.9552 mmHg1.4435651.5398 mmHg1.2883

YV =

1445.9552mmHg0.38571.4435
=0.6096
1320.7212 mmHg
2

1.61980.3857
=1.4426
0.9227(10.3857 )
Cv=exp

0.92270.3857
=1.2888
1.6198(10.3857 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2888

=0.3860
1445.9552 mmHg1.4426651.5398mmHg1.2888

YV =

1445.9552mmHg0.38601.4426
=0.6096
1320.7212 mmHg

1.61980.3860 2
1.6198 1+
=1.4421
0.9227(10.3860 )
Cv=exp

0.92270.3860 2
0.9227 1+
=1.2891
1.6198(10.3860 )
Cp=exp

XV =

1320.7212 mmHg651.5398 mmHg1.2891

=0.3861
1445.9552 mmHg1.4421651.5398 mmHg1.2891

YV =

1445.9552mmHg0.38611.4421
=0.6096
1320.7212 mmHg

1.61980.3861 2
=1.4417
0.9227(10.3861 )
Cv=exp

0.92270.3861 2
=1.2893
1.6198(10.3861 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg651.5398 mmHg1.2893

=0.3862
1445.9552 mmHg1.4417651.5398mmHg1.2893

YV =

1445.9552mmHg0.38621.4417
=0.6096
1320.7212 mmHg

@T =98.3064 C

1.61980.6998 2
1.6198 1+
=1.0645
0.9227(10.6998 )
Cv=exp

0.92270.6998 2
0.9227 1+
=1.8146
1.6198(10.6998 )
Cp=exp

XV =

1320.7212 mmHg715.0959 mmHg1.8146

=0.0601
1580.5614 mmHg1.0645715.0959 mmHg1.8146

YV =

1580.5614 mmHg0.06011.0645
=0.0765
1320.7212mmHg
2

1.61980.0601
=3.7042
0.9227(10.0601 )
Cv=exp

0.92270.0601 2
=1.0094
1.6198(10.0601 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg715.0959 mmHg1.0094

=0.1167
1580.5614 mmHg3.7042715.0959 mmHg1.0094

YV =

1580.5614 mmHg0.11673.7042
=0.5172
1320.7212 mmHg

1.61980.1167 2
=2.9078
0.9227(10.1167 )
Cv=exp

0.92270.1167 2
=1.0332
1.6198(10.1167 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

YV =

1320.7212mmHg715.0959 mmHg1.0332
=0.1509
1580.5614 mmHg2.9078715.0959 mmHg1.0332

1580.5614 mmHg0.15092.9078
=0.5250
1320.7212mmHg
2

1.61980.1509
=2.5630
0.9227(10.1509 )
Cv=exp

0.92270.1509 2
=1.0535
1.6198(10.1509 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212mmHg715.0959 mmHg1.0535
=0.1720
1580.5614 mmHg2.5630715.0959 mmHg1.0535

YV =

1580.5614 mmHg0.17202.5630
=0.5277
1320.7212mmHg

1.61980.1720 2
=2.3860
0.9227(10.1720 )
Cv=exp

0.92270.1720
=1.0681
1.6198(10.1720 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg715.0959 mmHg1.0681
=0.1852
1580.5614 mmHg2.3860715.0959 mmHg1.0681

YV =

1580.5614 mmHg0.18522.3860
=0.5288
1320.7212mmHg

1.61980.1852 2
=2.2880
0.9227(10.1852 )
Cv=exp

0.92270.1852 2
=1.0779
1.6198(10.1852 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212mmHg715.0959 mmHg1.0779
=0.1933
1580.5614 mmHg2.2880715.0959 mmHg1.0779

YV =

1580.5614 mmHg0.19332.2880
=0.5292
1320.7212mmHg
2

1.61980.1933
=2.2316
0.9227(10.1933 )
Cv=exp

0.92270.1933 2
=1.0842
1.6198(10.1933 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212mmHg715.0959 mmHg1.0842
=0.1982
1580.5614 mmHg2.2316715.0959 mmHg1.0842

YV =

1580.5614 mmHg0.19822.2316
=0.5293
1320.7212mmHg

1.61980.1982 2
=2.1985
0.9227(10.1982 )
Cv=exp

0.92270.1982
=1.0882
1.6198(10.1982 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg715.0959 mmHg1.0882
=0.2012
1580.5614 mmHg2.1985715.0959 mmHg1.0882

YV =

1580.5614 mmHg0.20122.1985
=0.5294
1320.7212mmHg

1.61980.2012 2
=2.1789
0.9227(10.2012 )
Cv=exp

0.92270.2012 2
=1.0906
1.6198(10.2012 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212mmHg715.0959 mmHg1.0906
=0.2030
1580.5614 mmHg2.1789715.0959 mmHg1.0906

YV =

1580.5614 mmHg0.20302.1789
=0.5294
1320.7212mmHg
2

1.61980.2030
=2.1672
0.9227(10.2030 )
Cv=exp

0.92270.2030 2
=1.0921
1.6198(10.2030 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg715.0959 mmHg1.0921

=0.2041
1580.5614 mmHg2.1672715.0959 mmHg1.0921

YV =

1580.5614 mmHg0.20412.1672
=0.5294
1320.7212mmHg

1.61980.2041 2
=2.1601
0.9227(10.2041 )
Cv=exp

0.92270.2041
=1.0930
1.6198(10.2041 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg715.0959 mmHg1.0930

=0.2048
1580.5614 mmHg2.1601715.0959 mmHg1.0930

YV =

1580.5614 mmHg0.20482.1601
=0.5294
1320.7212mmHg

1.61980.2048 2
=2.1559
0.9227(10.2048 )
Cv=exp

0.92270.2048 2
=1.0936
1.6198(10.2048 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg715.0959 mmHg1.0936
=0.2052
1580.5614 mmHg2.1559715.0959 mmHg1.0936

YV =

1580.5614 mmHg0.20522.1559
=0.5294
1320.7212mmHg
2

1.61980.2052
=2.1534
0.9227(10.2052 )
Cv=exp

0.92270.2052 2
=1.0939
1.6198(10.2052 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg715.0959mmHg1.0939
=0.2054
1580.5614 mmHg2.1534715.0959 mmHg1.0939

YV =

1580.5614 mmHg0.20542.1534
=0.5294
1320.7212 mmHg

1.61980.2054 2
=2.1519
0.9227(10.2054 )
Cv=exp

0.92270.2054
=1.0941
1.6198(10.2054 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg715.0959 mmHg1.0941
=0.2056
1580.5614 mmHg2.1519715.0959 mmHg1.0941

YV =

1580.5614 mmHg0.20562.1519
=0.5294
1320.7212mmHg

1.61980.2056 2
=2.1509
0.9227(10.2056 )
Cv=exp

0.92270.2056 2
=1.0942
1.6198(10.2056 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212mmHg715.0959 mmHg1.0942
=0.2057
1580.5614 mmHg2.1509715.0959 mmHg1.0942

YV =

1580.5614 mmHg0.20572.1509
=0.5294
1320.7212mmHg

@T =100.8571 C

1.61980.5705 2
=1.1571
0.9227(10.5705 )
Cv=exp

0.92270.5705 2
=1.5713
1.6198(10.5705 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg783.7377 mmHg1.5713

=0.1167
1725.0377 mmHg1.1571783.7377 mmHg1.5713

YV =

1725.0377 mmHg0.11671.1571
=0.1764
1320.7212 mmHg
2

1.61980.1167
1.6198 1+
=2.9076
0.9227(10.1167 )
Cv=exp

0.9227 1+

0.92270.1167
=1.0332
1.6198(10.1167 )
Cp=exp

XV =

1320.7212 mmHg783.7377 mmHg1.0332

=0.1215
1725.0377 mmHg2.9076783.7377 mmHg1.0332

YV =

1725.0377 mmHg0.12152.9076
=0.4613
1320.7212mmHg

1.61980.1215 2
=2.8543
0.9227(10.1215 )
Cv=exp

0.92270.1215 2
=1.0358
1.6198(10.1215 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg783.7377 mmHg1.0358

=0.1238
1725.0377 mmHg2.8543783.7377 mmHg1.0358

YV =

1725.0377 mmHg0.12382.8543
=0.4614
1320.7212mmHg

1.61980.1238 2
=2.8294
0.9227(10.1238 )
Cv=exp

0.92270.1238 2
=1.0371
1.6198(10.1238 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg783.7377 mmHg1.0371
=0.1249
1725.0377 mmHg2.8294783.7377 mmHg1.0371

YV =

1725.0377 mmHg0.12492.8294
=0.4614
1320.7212mmHg

1.6198 1+

1.61980.1249
=2.8177
0.9227(10.1249 )
Cv=exp

0.9227 1+

0.92270.1249
=1.0377
1.6198(10.1249 )
Cp=exp

XV =

1320.7212mmHg783.7377 mmHg1.0377
=0.1254
1725.0377 mmHg2.8177783.7377 mmHg1.0377

YV =

1725.0377 mmHg0.12542.8177
=0.4614
1320.7212mmHg

1.61980.1254 2
=2.8122
0.9227(10.1254 )
Cv=exp

0.92270.1254 2
=1.0380
1.6198(10.1254 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg783.7377 mmHg1.0380

=0.1256
1725.0377 mmHg2.8122783.7377 mmHg1.0380

YV =

1725.0377 mmHg0.12562.8122
=0.4614
1320.7212mmHg

1.61980.1256 2
=2.8095
0.9227(10.1256 )
Cv=exp

0.92270.1256 2
=1.0381
1.6198(10.1256 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg783.7377 mmHg1.0381

=0.1257
1725.0377 mmHg2.8095783.7377 mmHg1.0381

YV =

1725.0377 mmHg0.12572.8095
=0.4614
1320.7212mmHg

1.6198 1+

1.61980.1257
=2.8083
0.9227(10.1257 )
Cv=exp

0.9227 1+

0.92270.1257
=1.0382
1.6198(10.1257 )
Cp=exp

XV =

1320.7212 mmHg783.7377 mmHg1.0382

=0.1258
1725.0377 mmHg2.8083783.7377 mmHg1.0382

YV =

1725.0377 mmHg0.12582.8083
=0.4614
1320.7212mmHg

@T =103.4077 C
2

1.61980.4529
=1.3088
0.9227(10.4529 )
Cv=exp

0.92270.4529 2
=1.3824
1.6198(10.4529 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg857.7769 mmHg1.3824

=0.1059
1879.8956 mmHg1.3088857.7769 mmHg1.3824

YV =

1879.8956 mmHg0.10591.3088
=0.1972
1320.7212mmHg

1.61980.1059 2
=3.0352
0.9227(10.1059 )
Cv=exp

0.92270.1059
=1.0277
1.6198(10.1059 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg857.7769 mmHg1.0277

=0.091
1879.8956 mmHg3.0352857.7769 mmHg1.0277

YV =

1879.8956 mmHg0.09103.0352
=0.3933
1320.7212 mmHg

1.61980.0910
=3.2272
0.9227(10.0910 )
Cv=exp

0.92270.0910 2
=1.0208
1.6198(10.0910 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg857.7769 mmHg1.0208

=0.0857
1879.8956 mmHg3.2272857.7769 mmHg1.0208

YV =

1879.8956 mmHg0.08573.2272
=0.3938
1320.7212mmHg

1.6198 1+

1.61980.0857 2
=3.3010
0.9227(10.0857 )
Cv=exp

0.92270.0857
0.9227 1+
=1.0186
1.6198(10.0857 )
Cp=exp

XV =

1320.7212 mmHg857.7769 mmHg1.0186

=0.0838
1879.8956 mmHg3.3010857.7769 mmHg1.0186

YV =

1879.8956 mmHg0.08383.3010
=0.3939
1320.7212mmHg

1.61980.0838 2
=3.3283
0.9227(10.0838 )
Cv=exp

0.92270.0838 2
=1.0178
1.6198(10.0838 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg857.7769 mmHg1.0178

=0.0831
1879.8956 mmHg3.3283857.7769 mmHg1.0178

YV =

1879.8956 mmHg0.08313.3283
=0.3939
1320.7212 mmHg

1.61980.0831
=3.3382
0.9227(10.0831 )
Cv=exp

0.92270.0831 2
=1.0176
1.6198(10.0831 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg857.7769 mmHg1.0176

=0.0829
1879.8956 mmHg3.3382857.7769 mmHg1.0176

YV =

1879.8956 mmHg0.08293.3382
=0.3939
1320.7212 mmHg

1.6198 1+

1.61980.0829 2
=3.3418
0.9227(10.0829 )
Cv=exp

0.92270.0829
0.9227 1+
=1.0175
1.6198(10.0829 )
Cp=exp

XV =

1320.7212 mmHg857.7769 mmHg1.0175

=0.0828
1879.8956 mmHg3.3418857.7769 mmHg1.0175

YV =

1879.8956 mmHg0.08283.3418
=0.3939
1320.7212mmHg

@T =105.9584 C

0.92270.3458
=1.2383
1.6198(10.3458 )
Cp=exp

0.9227 1+

XV =

1.61980.3458
=1.5462
0.9227(10.3458 )
Cv=exp

1.6198 1+

1320.7212 mmHg937.5375 mmHg1.2383

=0.0798
2045.6598 mmHg1.5462937.5375 mmHg1.2383

YV =

2045.6598 mmHg0.07981.5462
=0.1911
1320.7212 mmHg

1.61980.0798 2
=3.3874
0.9227(10.0798 )
Cv=exp

0.92270.0798 2
=1.0162
1.6198(10.0798 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg937.5375 mmHg1.0162
=0.0616
2045.6598 mmHg3.3874937.5375 mmHg1.0162

YV =

2045.6598 mmHg0.06163.3874
=0.3230
1320.7212mmHg
2

1.61980.0616
=3.6785
0.9227(10.0616 )
Cv=exp

0.92270.0616
=1.0099
1.6198(10.0616 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg937.5375 mmHg1.0099

=0.0568
2045.6598 mmHg3.6785937.5375 mmHg1.0099

YV =

2045.6598 mmHg0.05683.6785
=0.3239
1320.7212mmHg

1.61980.0568 2
1.6198 1+
=3.7610
0.9227(10.0568 )
Cv=exp

0.92270.0568 2
0.9227 1+
=1.0085
1.6198(10.0568 )
Cp=exp

XV =

1320.7212 mmHg937.5375 mmHg1.0085

=0.0556
2045.6598 mmHg3.7610937.5375 mmHg1.0085

YV =

2045.6598 mmHg0.05563.7610
=0.3239
1320.7212mmHg

1.61980.0556 2
=3.7831
0.9227(10.0556 )
Cv=exp

0.92270.0556 2
=1.0081
1.6198(10.0556 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg937.5375 mmHg1.0081

=0.0553
2045.6598 mmHg3.7831937.5375 mmHg1.0081

YV =

2045.6598 mmHg0.05533.7831
=0.3239
1320.7212 mmHg
2

1.61980.0553
=3.7889
0.9227(10.0553 )
Cv=exp

0.92270.0553
=1.0080
1.6198(10.0553 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

YV =

1320.7212 mmHg937.5375 mmHg1.0080

=0.0552
2045.6598 mmHg3.7889937.5375 mmHg1.0080

2045.6598 mmHg0.05523.7889
=0.3239
1320.7212 mmHg

@T =108.5090 C
2

1.61980.2479
=1.9155
0.9227(10.2479 )
Cv=exp

0.92270.2479 2
=1.1320
1.6198(10.2479 )
Cp=exp

1.6198 1+

0.9227 1+

XV =( 1320.7212 mmHg1023.3563 mmHg1.1320 )

YV =

2222.8683 mmHg0.05241.9155
=0.1688
1320.7212mmHg

1.61980.0524 2
=3.8420
0.9227(10.0524 )
Cv=exp

0.92270.0524 2
=1.0072
1.6198(10.0524 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg1023.3563 mmHg1.0072

=0.0386
2222.8683 mmHg3.84201023.3563 mmHg1.0072

YV =

2222.8683 mmHg0.03863.8420
=0.2497
1320.7212mmHg

1.61980.0386 2
=4.1102
0.9227(10.0386 )
Cv=exp

0.92270.0386 2
=1.0040
1.6198(10.0386 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg1023.3563 mmHg1.0040

=0.0362
2222.8683 mmHg4.11021023.3563 mmHg1.0040

YV =

2222.8683 mmHg0.03624.1102
=0.2502
1320.7212 mmHg
2

1.61980.0362
1.6198 1+
=4.1611
0.9227(10.0362 )
Cv=exp

0.92270.0362
0.9227 1+
=1.0035
1.6198(10.0362 )
Cp=exp

XV =

1320.7212 mmHg1023.3563 mmHg1.0035

=0.0357
2222.8683 mmHg4.16111023.3563 mmHg1.0035

YV =

2222.8683 mmHg0.03574.1611
=0.2502
1320.7212 mmHg

1.61980.0357 2
=4.1704
0.9227(10.0357 )
Cv=exp

0.92270.0357 2
=1.0034
1.6198(10.0357 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212mmHg1023.3563mmHg1.0034
=0.0356
2222.8683 mmHg4.17041023.3563 mmHg1.0034

YV =

2222.8683 mmHg0.03564.1704
=0.2502
1320.7212 mmHg

@T =111.0597 C

1.61980.1582 2
=2.4986
0.9227(10.1582 )
Cv=exp

0.92270.1582 2
=1.0584
1.6198(10.1582 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg1115.5828 mmHg1.0584

=0.0289
2412.0720 mmHg2.49861115.5828mmHg1.0584

YV =

2412.0720 mmHg0.02892.4986
=0.1318
1320.7212mmHg

1.61980.0289 2
1.6198 1+
=4.3192
0.9227(10.0289 )
Cv=exp

0.9227 1+

0.92270.0289
=1.0023
1.6198(10.0289 )
Cp=exp

XV =

1320.7212 mmHg1115.5828 mmHg1.0023

=0.0218
2412.0720 mmHg4.31921115.5828 mmHg1.0023

YV =

2412.0720 mmHg0.02184.3192
=0.1718
1320.7212mmHg

1.61980.0218 2
=4.4826
0.9227(10.0218 )
Cv=exp

0.92270.0218 2
=1.0013
1.6198(10.0218 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

YV =

1320.7212mmHg1115.5828mmHg1.0013
=0.0210
2412.0720 mmHg4.4 8261115.5828mmHg1.0013

2412.0720 mmHg0.02104.4826
=0.1720
1320.7212mmHg

1.61980.0210 2
=4.5011
0.9227(10.0210 )
Cv=exp

0.92270.0210 2
=1.0012
1.6198(10.0210 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =(1320.7212mmHg1115.5828mmHg1.0012)/( 2412.0720mmHg4.50111115.5828 mmHg1.0012

YV =(2412.0720 mmHg0.02094.5011)/1320.7212mmHg=0.1720
@T =113.6103 C
2

1.61980.0759
1.6198 1+
=3.4469
0.9227(10.0759 )
Cv=exp

0.9227 1+

0.92270.0759
=1.0147
1.6198(10.0759 )
Cp=exp

XV =

1320.7212 mmHg1214.5793 mmHg1.0147

=0.0113
2613.8341 mmHg3.44691214.5793 mmHg1.0147

YV =

2613.8341mmHg0.01133.4469
=0.0774
1320.7212 mmHg

1.61980.0113 2
=4.7420
0.9227(10.0113 )
Cv=exp

0.92270.0113 2
=1.0004
1.6198(10.0113 )
Cp=exp

1.6198 1+

0.9227 1+

)
)

XV =

1320.7212 mmHg1214.5793 mmHg1.0004

=0.0095
2613.8341 mmHg4.74201214.5793 mmHg1.0004

YV =

2613.8341mmHg0.00954.7420
=0.0887
1320.7212mmHg

1.61980.0095 2
=4.7915
0.9227(10.0095 )
Cv=exp

0.92270.0095 2
=1.0003
1.6198(10.0095 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg1214.5793 mmHg1.0003

=0.0094
2613.8341 mmHg4.79151214.5793 mmHg1.0003

YV =

2613.8341mmHg0.00944.7915
=0.0887
1320.7212mmHg

@T =116.1610 C

1.61980.0000
=5.0521
0.9227(10.0000 )
Cv=exp

0.92270.0000 2
=1.0000
1.6198(10.0000 )
Cp=exp

1.6198 1+

0.9227 1+

XV =

1320.7212 mmHg1320.7212 mmHg1.0000

=0.0000
2828.7302 mmHg5.05211320.7212 mmHg1.0000

YV =

2828.7302mmHg0.00005.0521
=0.0000
1320.7212 mmHg

Diagramas para comportamiento ideal

Diagramas de comportamiento no ideal

Diagramas de Mc Cabe Thiele en comportamiento Ideal y Real

TC =

NET 1
100
NPR
NPR= 16

TC =

Real

TC =

21
100=6.25
16

NET 1
100
NPR
NPR= 16

TC =

11
100=0
16

Debido al comportamiento no ideal de la mezcla no se puede emplear el

diagrama de
Mc Cabe Thiele sin la correccin de Van Laar

Diagramas de Mc Cabe Thiele en comportamiento Real Corte 1

R X
X
y= e w + D
R e +1 Re + 1
y=mx +b

=b
y

L=0.25

L
min

D=0.15

L
min

0.25 L
L
min
Re = =
=1.6667
D 0.15 L
min

XD
.5671
NET 1 = R +1 = 1.6667+1 =.2127
TC =
100 e
NPR
y
NPR= 16

31
TC =
100=12.5
16

Diagramas de Mc Cabe Thiele en comportamiento Real Corte 2

R X
X
y= e w + D
R e +1 Re + 1
y=mx +b

=b
y

L=0.25

L
min

D=0.15

L
min

0.25 L
L
min
Re = =
=1.6667
D 0.15 L
min

XD
.5 078
NET 1 = R +1 = 1.6667+1 =.1904
TC =
100 e
NPR
y
NPR= 16

21
TC =
100=6.25
16

Diagramas de Mc Cabe Thiele en comportamiento Real Corte 3

R X
X
y= e w + D
R e +1 Re + 1
y=mx +b

=b
y

L=0.25

L
min

D=0.15

L
min

0.25 L
L
min
Re = =
=1.6667
D 0.15 L
min

XD
0.4893
NET 1 = R +1 = 1.6667+1 =0 . 1834
TC =
100 e
NPR
y
NPR= 16

31
TC =
100=12.5
16

Diagramas de Mc Cabe Thiele en comportamiento Real Corte 4

L=0.25

L
min

D=0.15

L
min

0.25 L
L
min
Re = =
=1.6667
D 0.15 L
min

y=

ReX w X D
+
R e +1 Re + 1

y=mx +b

=b
y

TC =

NET 1
100
NPR
NPR= 16

TC =

31
100=12.5
16

Diagramas de Mc Cabe Thiele en comportamiento Real Corte 5

R X
X
y= e w + D
R e +1 Re + 1
y=mx +b

=b

L=0.25

L
min

D=0.15

L
min

0.25 L
L
min
Re = =
=1.6667
D 0.15 L
min

TC =

NET 1
100
NPR
NPR= 16

31
TC =
100=12.5
16

Carga en el hervidor

W o=

V oo
o
PM
22 L 0.984 Kg

W o=

Wf =

(
)
0.0329 + 18.015
)(
L

[(

46.07

Kg
Kmol

Kg ( 0.9671 )
Kmol

V f f
f
PM
17.092 L 0 .985 Kg

Wf =

[(

46.07

Kg
Kmol

)(

L
min

+0.25

0.4

[(

46.07

Kg
Kmol

[(

46.07

Kg
Kmol

[(

46.07

Kg
Kmol

[(

46.07

Kg
Kmol

L
min

)]

Kg
Kmol

0 .854 Kg
L

)(

( 10.0244 )

=0.8371Kmol

L
min

Kg
Kmol

0 .845 Kg

0.5078 + 18.015

(10.5671 )

)]

Kg
Kmol

( 10.5078 )

)]

=0.0100 Kmol
min

=0.0106 Kmol
min

0 .855 Kg

(
)
=0.0108
0.4893 + 18.015 ( 10.4893 )
)(
)]
L
min

Kg
Kmol

0.4
V 4=

=0.40

)(

0.4

V 3=

L
min

L
min

0.5671 + 18.015

0.4
V 2=

0.0244 + 18.015

V 1 5=L+ D=0.15

V 1=

)]

=1.1431Kmol

L
min

0 .87 Kg

)(

0.454 + 18.015

Kg
Kmol

( 10.454 )

)]

Kmol
min

=0.0113 Kmol
min

0.4
V 5=

t=

[(

46.07

Kg
Kmol

L
min

0 .867 Kg

)(

0.4483 + 18.015

Kg
Kmol

( 10.4483 )

)]

=0.0113 Kmol
min

R e +1
( W oW f )
V

t1 =

0.4 +1
( 1.1431 Kmol0.8371 Kmol )=42.8400min
0.0100 Kmol
min

t2 =

0.4+1
( 1.1431 Kmol0.8371 Kmol )=40.4151min
0.0106 Kmol
min

t3 =

0.4+1
( 1.1431 Kmol0.8371 Kmol )=39.6667 min
0.0108 Kmol
min

t 4=

0.4+1
( 1.1431 Kmol0.8371 Kmol )=37.9115 min
0.0113 Kmol
min

t5 =

0.4 +1
( 1.1431Kmol 0.8371Kmol ) =37.9115min
0.0113 Kmol
min

ln

Wf
1
= h F X
Wo 3

( )

h=

X f Xo
8

h=

0.870.05
=0.1025
8

X n +1=X n h

Xf

Wf
dx
ln
=
Wo
yx
X

( )

1
1
1
1
F X =( yx
) +4 ( yx
) + 2( yx
) +( yx
)
1

ultimo

CONCLUSIONES

BIBLIOGRAFIA
ANEXOS